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US 10,480,278 B1Granted
Cement spacer fluid comprising quaternary surfactant, viscosifier, and proppant
AssigneeBaker Hughes, A Ge Company, LLC
InventorsThomas S. Sodhi, Shannon E. Bryant
Life of this patent
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Abstract
A method of cementing a wellbore penetrating a subterranean formation comprises: injecting into the wellbore a cement spacer fluid comprising a carrier fluid, a quaternary surfactant, a viscosifier, and a proppant; injecting a cement slurry into the wellbore; and allowing the cement slurry to set.
Claims18
A method of cementing a wellbore penetrating a subterranean formation, the method comprising:
- injecting into the wellbore a cement spacer fluid comprising a carrier fluid, a quaternary surfactant, a viscosifier, and a proppant;
- injecting a cement slurry into the wellbore;
- and
- allowing the cement slurry to set,
- wherein the carrier fluid comprises water;
- the proppant comprises ceramic particles, sand, a nut shell, gravel, glass, or a combination comprising at least one of the foregoing;
- the quaternary surfactant has a cation of R1 R2 R3 R4N+ and an anion, wherein R1, R2, R3 and R4 are each independently a straight or branched C1-30 alkyl group, a C7-30 alkylbenzyl group, a C7-30 arylalkyl group, a straight or branched C3-30 alkenyl group, a C1-30 hydroxyalkyl group, a C7-30 hydroxyalkylbenzyl group, or a polyoxyalkylene group;
- and the anion comprises a halide, a perchlorate, a thiocyanate, a cyanate, a carboxylate, an alkyl sulfate, an alkyl sulfonate, PF6−, AsF6−, SbF6−, NO2−, NO3−, SO4−, or BX4−, wherein X is a halide;
- the viscosifier comprises guar gums, guar derivatives, hydratable polysaccharides, xanthan gum, galactomannan gums, glucomannan gums, cellulose, cellulose derivatives, poly((meth)acrylic acid)s, poly((meth)acrylamides), copolymers of (meth)acrylic acid and (meth)acrylamide, C1-8 alkyl poly(meth)acrylates, clays, or a combination comprising at least one of the foregoing viscosifiers;
- and
- the cement spacer fluid comprises about 30 to about 100 wt % of the carrier fluid, about 0.05 to about 10 wt % of the quaternary surfactant, about 0.05 to about 10 wt % of the viscosifier, and about 1 to about 65 wt % of the proppant, each based on the weight of water in the cement spacer fluid.
8 more elements
A cement spacer fluid comprising:
- about 30 to about 100 wt % of an aqueous carrier comprising water;
- about 0.05 to about 10 wt % of a quaternary surfactant having a cation of R1 R2 R3 R4N+ and an anion, wherein R1, R2, R3, and R4 are each independently a straight or branched C1-30 alkyl group, a C7-30 alkylbenzyl group, a C7-30 arylalkyl group, a straight or branched C3-30 alkenyl group, a C1-30 hydroxyalkyl group, a C7-30 hydroxyalkylbenzyl group, or a polyoxyalkylene group;
- and the anion comprises a halide, a perchlorate, a thiocyanate, a cyanate, a carboxylate, an alkyl sulfate, an alkyl sulfonate, PF6−, AsF6−, SbF6−, NO2−, NO3−, SO4−, or BX4−, X being a halide;
- about 0.05 to about 10 wt % of a viscosifier comprising guar gums, guar derivatives, hydratable polysaccharides, xanthan gum, galactomannan gums, glucomannan gums, cellulose, cellulose derivatives, poly((meth)acrylic acid)s, poly((meth)acrylamides), copolymers of (meth)acrylic acid and (meth)acrylamide, C1-8 alkyl poly(meth)acrylates, or clays or a combination comprising at least one of the foregoing viscosifiers;
- and
- about 1 to about 65 wt % of a proppant,
- each based on the weight of water in the cement spacer fluid, the proppant comprising ceramic particles, sand, a nut shell, gravel, glass, or a combination comprising at least one of the foregoing.
4 more elements
Dependencies are inferred from the claim text.