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US 10,479,893 B2Granted
Preparation of iron (III) oxide pigment
AssigneeLANXESS Deutschland GmbH
InventorsWaldemar Czaplik, Guido Ketteler, Jurgen Kischkewitz
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Abstract
The present invention relates to an improved process for producing iron oxide red pigments by the Penniman process using nitrate (also referred to as nitrate process or direct red process).
Claims14
A process for producing haematite pigments, the process comprising:
- contacting iron, an aqueous haematite nucleus suspension containing haematite nuclei which have a particle size of 100 nm or less and a specific BET surface area of 40 m2/g to 150 m2/g (measured in accordance with DIN 66131), and an iron(II) nitrate solution, in the presence of at least one oxygen-containing gas at temperatures of 70 to 99° C. to produce a suspension comprising haematite pigment,
- wherein the aqueous solution of the iron, the haematite nucleus suspension, and the iron(II) nitrate solution is mixed by means of hydraulic mixing;
- wherein the hydraulic mixing is carried out by means of at least one pump which takes a liquid phase from a reactor at an outlet and feeds it back into the reactor at another place by an inlet, and
- wherein the at least one oxygen-containing gas is introduced into the aqueous solution with a gas introduction volume of 6 m3 of gas volume/m3 of batch volume/hour or less.
1 more element
Dependencies are inferred from the claim text.