Polybutylene terephthalate composition with improved hydrolytic stability
AssigneeSabic Global Technologies B.V.
InventorsHusnu Alp Alidedeoglu, Yuzhen Yang, Prashant Kumar
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Abstract
The present invention relates to a thermoplastic composition with improved hydrolytic stability, comprising: 30 to 50 percent by weight of a polybutylene terephthalate (PBT) having a carboxylic end group concentration (CEG) of 40 to 120 mmol/kg and an intrinsic viscosity of 0.63 to 0.68 dl/g as measured in a 60:40 phenol/tetrachloroethane; 0.01 to 0.1 percent by weight of a catalyst; 0.01 to 5 percent by weight of an epoxy chain extender; wherein all weight percents are based on the total weight of the composition.
Claims10
A thermoplastic composition with improved hydrolytic stability, comprising:
- 10 to 30 percent by weight of polybutylene terephthalate (PBT) having a carboxylic end group concentration (CEG) of 40 to 50 mmol/kg, and an intrinsic viscosity of 1.15 to 1.25 dl/g as measured in a 60:40 phenol/tetrachloroethane;
- 30 to 50 percent by weight of a polybutylene terephthalate (PBT) having a carboxylic end group concentration (CEG) of 50 to 120 mmol/kg and an intrinsic viscosity of 0.63 to 0.68 dl/g as measured in a 60:40 phenol/tetrachloroethane;
- 25 to 35 weight percent of a reinforcing filler;
- 0.01 to 0.1 percent by weight of a catalyst;
- 0.01 to 5 percent by weight of an epoxy chain extender;
- 0.01 to 0.1 percent by weight of a hindered phenol stabilizer;
- and
- 0.1 to 10 percent by weight of a mold release agent;
- wherein all weight percents are based on the total weight of the composition;
- and
- wherein the melt volume flow rate as measured by ISO 1133 at 250° C. with 5 kg load and 300 s dwell time of the thermoplastic composition when subjected to 80° C. and 70 percent room humidity after 500 hours is between 52 and 62 cm3/10 min, and the melt volume flow rate percent change compared to an initial melt volume flow rate of the thermoplastic composition is between 20 and 40 percent.
A thermoplastic composition with improved hydrolytic stability, comprising:
- 10 to 30 percent by weight of polybutylene terephthalate (PBT) having a carboxylic end group concentration (CEG) of 40 to 50 mmol/kg, and an intrinsic viscosity of 1.2 cm3/g as measured in a 60:40 phenol/tetrachloroethane;
- 30 to 50 percent by weight of a polybutylene terephthalate (PBT) having a carboxylic end group concentration (CEG) of 40 to 120 mmol/kg and an intrinsic viscosity of 0.63 to 0.68 dL/g as measured in a 60:40 phenol/tetrachloroethane;
- 25 to 35 percent by weight of a reinforcing filler;
- 0.01 to 3 percent by weight of an epoxy chain extender;
- 0.01 to 0.1 percent by weight of a hindered phenol stabilizer;
- 0.01 to 0.1 percent by weight of a catalyst;
- and
- 0.1 to 10 percent by weight of a mold release agent;
- wherein all weight percents are based on the total weight of the composition;
- and
- wherein the melt volume flow rate as measured by ISO 1133 at 250° C. with 5 kg load and 300 s dwell time of the thermoplastic composition when subjected to 80° C. and 70 percent room humidity after 500 hours is between 52 and 62 cm3/10 min, and the melt volume flow rate percent change compared to an initial melt volume flow rate of the thermoplastic composition is between 20 and 40 percent.
Dependencies are inferred from the claim text.