Lithium secondary battery
AssigneeSK Innovation Co., Ltd.
InventorsKyung-Bin Yoo, Kook-Hyun Han, Duck-Chul Hwang
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Abstract
The present invention relates to a lithium secondary battery, and more specifically, to a lithium secondary battery including a cathode, an anode and a non-aqueous electrolyte solution, where the cathode includes a cathode active material including a lithium-metal oxide which is doped with a transition metal and includes at least one type of metal having a concentration gradient region between a central portion and a surface portion, and thus having a significantly increased charge/discharge capacity and output at a low temperature to exhibit excellent properties in the low-temperature environment.
Claims12
A lithium secondary battery, comprising:
- a cathode;
- an anode;
- and
- a non-aqueous electrolyte solution,
- wherein the cathode includes a cathode active material including a lithium-metal oxide which is doped with a dopant element,
- wherein the lithium-metal oxide is represented by Formula 1 below,
- LixM1aM2bM3cOy Formula 1
- wherein M1, M2 and M3 are selected from a group consisting of Ni, Co, Mn, Na, Mg, Ca, Ti, V, Cr, Cu, Zn, Ge, Sr, Ag, Ba, Zr, Nb, Mo, Al, Ga and B,
- 0<x≤1.1, 2≤y≤2.02, 0<a<1, 0<b<1, 0<c<1, and 0<a+b+c≤1,
- wherein the cathode active material comprises
- a central portion within 0.1 μm to 0.2 μm radius from a center of the cathode active material;
- a surface portion within 0.1 μm but not less than 0.05 μm from an outmost portion of the cathode active material;
- and
- an intermediate region between the central portion and the surface portion, the intermediate region comprising a concentration gradient region wherein M1 and M3 have a concentration gradient in a direction from the central portion to the surface portion, and a non-concentration gradient region wherein M1 and M3 do not have a concentration gradient in a direction from the central portion to the surface portion;
- and
- wherein M2 has a constant concentration throughout the cathode active material from the central portion to the surface portion.
Dependencies are inferred from the claim text.