Te-free AsSeGe chalcogenides for selector devices and memory devices using same

A switching device, comprising:

• a first electrode;
• a second electrode;
• and
• a switching layer between the first and second electrodes, the switching layer comprising a composition of arsenic As in a range of 15 at % to 46 at %, selenium Se in a range of 27 at % to 60 at % and germanium Ge in a range of 20 at % to 25 at %, wherein the composition of the switching layer is tellurium Te-free and includes As, Se and Ge in amounts effective to switch the switching layer using an applied voltage pulse less than 50 ns in duration at a threshold voltage Vt>3V, with an off-state leakage current IOFF<1 nA.

A memory device, comprising:

• a first electrode;
• a second electrode;
• a memory element in contact with the first electrode;
• a switching layer in series with the memory element between the first and second electrodes, the switching layer comprising a tellurium Te-free composition of arsenic As (15 at % to 46 at %), selenium Se (27 at % to 60 at %) and germanium Ge (10 at % to 25 at %);
• and
• a barrier layer between the memory element and the switching layer, wherein the switching layer is less than 50 nm thick, and the composition includes As, Se and Ge in amounts effective to switch the switching layer using an applied voltage pulse less than 50 ns in duration at a threshold voltage Vt>3V, with an off-state leakage current IOFF<1 nA.