Chemically amplified resist composition and patterning process
AssigneeShin-Etsu Chemical Co., Ltd.
InventorJun Hatakeyama
Life of this patent
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Abstract
A chemically amplified resist composition comprising a quencher containing an iodonium iodide and an acid generator exhibits a sensitizing effect and an acid diffusion suppressing effect and forms a pattern having improved resolution, LWR and CDU.
Claims14
A chemically amplified resist composition comprising, a quencher containing an iodonium iodide, and an acid generator,
- wherein the acid generator also functions as a base polymer, and
- the acid generator is a polymer comprising recurring units of at least one type selected from recurring units having the formulae (f1) to (f3):
- wherein RA is each independently hydrogen or methyl,
- Z1 is a single bond, phenylene, —O—Z11—, or —C(═O)—Z12—Z11—, Z11 is a C1-C6 straight, branched or cyclic alkylene group or C2-C6 straight, branched or cyclic alkenylene group which may contain a carbonyl, ester, ether or hydroxyl moiety, or phenylene group, Z12 is —O— or —NH—,
- R51, R52, R53, R54, R55, R56, R57, and R58 are each independently a C1-C12 straight, branched, or cyclic alkyl group which may contain a carbonyl ester or ether moiety or a C6-C12 aryl, C7-C20 aralkyl, or mercaptophenyl group,
- Z2 is a single bond, —Z21—C(═O)—O—, —Z21—O—, or —Z21—O—C(═O)—, Z21 is a C1-C12 straight, branched or cyclic alkylene group which may contain a carbonyl, ester or ether moiety,
- Z3 is a single bond, methylene, ethylene, phenylene, fluorinated phenylene, —O—Z31—, or —C(═O)—Z32—Z31, Z31 is a C1-C6 straight, branched or cyclic alkylene group or C2-C6 straight, branched or cyclic alkenylene group which may contain a carbonyl, ester, ether or hydroxyl moiety, or a phenylene, fluorinated phenylene or trifluoromethyl-substituted phenylene group, Z32 is —O— or —NH—,
- A1 is hydrogen or trifluoromethyl, and M− is a non-nucleophilic counter ion.
A chemically amplified resist composition comprising a quencher containing an iodonium iodide, an acid generator and a base polymer,
- wherein the base polymer comprises recurring units of at least one type selected from recurring units having the formulae (f1) to (f3):
- wherein RA is each independently hydrogen or methyl,
- Z1 is a single bond, phenylene, —O—Z11—, or —C(═O)—Z12—Z11—, Z11 is a C1-C6 straight, branched or cyclic alkylene group or C2-C6 straight, branched or cyclic alkenylene group which may contain a carbonyl, ester, ether or hydroxyl moiety, or phenylene group, Z12 is —O— or —NH—,
- R51, R52, R53, R54, R55, R56, R57 and R58 are each independently a C1-C12 straight, branched or cyclic alkyl group which may contain a carbonyl, ester or ether moiety, or a C6-C12 aryl, C7-C20 aralkyl, or mercaptophenyl group,
- Z2 is a single bond, —Z21—C(═O)—O—, —Z21—O—, or —Z21—O—C(═O)—, Z21 is a C1-C12 straight, branched or cyclic alkylene group which may contain a carbonyl, ester or ether moiety,
- Z3 is a single bond, methylene, ethylene, phenylene, fluorinated phenylene, —O—Z31—, or —C(═O)—Z32—Z31—, Z31 is a C1-C6 straight, branched or cyclic alkylene group or C2-C6 straight, branched or cyclic alkenylene group which may contain a carbonyl, ester, ether or hydroxyl moiety, or a phenylene, fluorinated phenylene or trifluoromethyl-substituted phenylene group, Z32 is —O— or —NH—,
- A1 is hydrogen or trifluoromethyl, and M− is a non-nucleophilic counter ion.
A chemically amplified resist composition comprising a quencher containing an iodonium iodide, an acid generator and a base polymer,
- wherein the base polymer comprises recurring units having the formula (a1) or recurring units having the formula (a2):
- wherein RA is each independently hydrogen or methyl, R11 and R12 are each independently an acid labile group, X1 is a single bond, phenylene, naphthylene, or a C1-C12 linking group containing ester moiety or lactone ring, and X2 is a single bond or ester group.
A chemically amplified resist composition comprising a quencher containing an iodonium iodide, an acid generator and a base polymer,
- wherein the base polymer is an acid labile group-free polymer.
Dependencies are inferred from the claim text.