Method for producing alkenyl ether polymer
AssigneeMaruzen Petrochemical Co., Ltd.
InventorShinji Sugihara
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AssigneeMaruzen Petrochemical Co., Ltd.
InventorShinji Sugihara
Estimating the term…
To provide a method for producing a polymer that is capable of providing an alkenyl ether polymer having a molecular weight, a molecular weight distribution, and a composition that are controlled, with a vinyl ether having a hydroxyl group, and a block copolymer thereof. To provide a polymer obtained by the method as a macro chain transfer agent capable of performing reversible addition fragmentation chain transfer polymerization. Livingness can be imparted to radical polymerization of a hydroxyl group-containing vinyl ether by performing the radical polymerization in the presence of a particular RAFT agent and a radical polymerization initiator, and a block copolymer with another radically polymerizable vinyl monomer can be obtained by using the resulting living polymer as a macro chain transfer agent capable of performing reversible addition fragmentation chain transfer polymerization.
A method for producing an alkenyl ether polymer, comprising at least performing living radical polymerization of an alkenyl ether having a hydroxyl group represented by formula (2):
A macro chain transfer agent comprising at least an end structure comprising a dithiocarbamate group represented by formula (3):
A macro chain transfer agent capable of performing reversible addition fragmentation chain transfer polymerization represented by formula (5):
Dependencies are inferred from the claim text.