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US 10,369,544 B1Granted
Method of synthesizing novel adsorbent titanosilicate material (UPRM-5) using NR4+ type cations
AssigneeUniversity of Puerto Rico
InventorsArturo J. Hernandez-Maldonado, Marietta E. Marcano-Gonzalez, Jose N. Primera-Pedrozo
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Abstract
The invention employs tetrapropylammonium (TPA+) and tetrabutylammonium (TBA+) as structure directing agents (SDAs), respectively for the preparation of the flexible titanium silicate UPRM-5. Both UPRM-5 variants are detemplated and modified to include extraframework Sr2+ and produce materials for carbon dioxide adsorption.
Claims4
A method of synthesizing a titanosilicate material comprising:
- adding a structure directing agent selected from the group consisting of:
- tetrapropylammonium (TPA+) and tetrabutylammonium (TBA+), that allows the formation of a porous adsorbent material, to a gel solution containing titanium (III) chloride solution in HCl and stirring for 30 minutes to prepare a gel mixture and crystallizing said gel mixture to form a titanosilicate porous material having structural faults introduced by said structure directing agent;
- removing said structure directing agent from said titanosilicate porous material via ion exchange with NH4+ to form a detemplated material;
- and
- functionalizing said detemplated material with strontium cation via ion exchange to form a titanosilicate porous material having a micropore area that varies as a function of thermal activation temperature due to said structural faults introduced by the structure directing agent, wherein the titanosilicate material having an unit cell selected from the group consisting of |Sr2+3.0Na+3.3OH−2.31|[Si11.4Ti8.3O37]:23H2O and |Sr2+2.4Na+3.9OH−1.5|[Si9.3Ti7.1O37]:20H2O.
2 more elements
Dependencies are inferred from the claim text.