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US 10,312,514 B2Granted
Positive electrode active material for lithium secondary battery, positive electrode for lithium secondary battery, and lithium secondary battery
AssigneeToyota Jidosha Kabushiki Kaisha
InventorRyuta Sugiura
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Abstract
A positive electrode active material for a lithium secondary battery includes a lithium transition metal complex oxide that has a spinel crystalline structure. This lithium transition metal complex oxide includes: manganese and nickel as main transition metal elements; titanium and iron as additive transition metal elements; and oxygen and fluorine.
Claims5
A positive electrode active material for a lithium secondary battery, the positive electrode active material comprising
- a lithium transition metal complex oxide having a spinel crystalline structure, wherein
- the lithium transition metal complex oxide includes:
- manganese and nickel as main transition metal elements;
- titanium and iron as additive transition metal elements;
- and
- oxygen and fluorine,
- wherein the lithium transition metal complex oxide is represented by a following general formula (I):
- LixMn2-a-b-c-dNiaTibFecMdO4-yFy (I)
- wherein
- M is at least one element selected from the group consisting of Al, Si, Mg, Ca, Ba, Sr, Sc, V, Cr, Co, Cu, Zn, Ga, Y, Ru Rh, Pd, In, Sn, Sb, La, Ce, Sm, Zr, Nb, Ta, Mo, W, B, C, P, and S,
- 0.9≤x≤1.3,
- 0.0005≤y≤0.1,
- 0.4≤a≤0.5,
- 0<b≤0.2,
- 0<c≤0.05, and
- 0≤d≤0.2.
13 more elements
Dependencies are inferred from the claim text.