Pesticidally active tetracyclic derivatives with sulfur containing substituents

A compound of formula I,

• wherein
• A is CH or N;
• X is S, SO or SO2;
• R1 is C1-C4alkyl, C2-C6alkenyl, C2-C6haloalkenyl, C2-C6alkynyl, C1-C4haloalkyl, C3-C6cycloalkyl, C3-C6cycloalkyl-C1-C4alkyl;
• or is C3-C6cycloalkyl mono- or polysubstituted by substituents selected from the group consisting of halogen, cyano, C1-C4haloalkyl and C1-C4alkyl;
• or is C3-C6cycloalkyl-C1-C4alkyl mono- or polysubstituted by substituents selected from the group consisting of halogen, cyano, C1-C4haloalkyl and C1-C4alkyl;
• R2 is hydrogen, halogen, C1-C4haloalkylsulfanyl, C1-C4haloalkylsulfinyl, C1-C4haloalkylsulfonyl, O(C1-C4haloalkyl), —SF5, —C(O)C1-C4haloalkyl, cyano, C1-C6haloalkyl or is C1-C6haloalkyl substituted by one or two substituents selected from the group consisting of hydroxyl, methoxy and cyano;
• or is C3-C6cycloalkyl which can be mono- or polysubstituted by substituents selected from the group consisting of halogen, cyano, C1-C4haloalkyl and C1-C4alkyl;
• G1 is N or CR4;
• G2 is N or CR5;
• G3 is O, S or NR6;
• R6 is C1-C4alkyl which can be mono- or polysubstituted by substituents selected from the group consisting of halogen and C1-C2alkylsulfinyl;
• R4 and R5, independently from each other, are hydrogen, halogen, cyano, nitro, C1-C6alkyl, C1-C6haloalkyl, or are C3-C6cycloalkyl which can be mono- or polysubstituted by R8;
• or are C3-C6cycloalkyl-C1-C4alkyl which can be mono- or polysubstituted by R9;
• or
• R4 and R5, independently from each other, are C2-C6alkenyl, C2-C6haloalkenyl, C2-C6alkynyl, C2-C6haloalkynyl, C1-C6haloalkoxy, C1-C6alkoxy, C1-C6alkylsulfanyl, C1-C4alkylsulfonyl, C1-C6alkylsulfinyl C1-C6haloalkylsulfanyl, C1-C4haloalkylsulfonyl, C1-C6haloalkylsulfinyl or hydroxyl;
• R8 and R9, independently from each other, are halogen, nitro, cyano, C1-C4haloalkoxy, C1-C4alkoxy, C1-C4alkyl or C1-C4haloalkyl;
• L1, L2, L3 and L4 form together with the two carbon atoms to which L1 and L4 are attached, an aromatic or partially saturated carbocyclic or heterocyclic ring system;
• wherein
• L1 is nitrogen, S(O)n, oxygen, N—R10a or C(R10a)m;
• L2 is nitrogen, S(O)n, oxygen, N—R10b or C(R10b)m;
• L3 is nitrogen, S(O)n, oxygen, N—R10c, or C(R10c)m;
• L4 is nitrogen, S(O)n, oxygen, a direct bond, N—R10d or C(R10d)m;
• with the provisos that no more than 2 substituents selected from L1, L2, L3 and L4 can be oxygen or sulfur;
• and if two L groups are oxygen, they are not adjacent to each other;
• and no more than three L groups can be nitrogen;
• n is 0 to 2;
• m is 1 or 2;
• R10a, R10b, R10c, and R10d, independently from each other, are hydrogen, halogen, nitro, cyano, amino, hydroxyl, C1-C6alkyl, C2-C6alkenyl, C2-C6alkynyl, C3-C6cycloalkyl, C1-C6haloalkyl, C2-C6haloalkenyl, C2-C6haloalkynyl, C3-C6halocycloalkyl, C1-C6alkoxy, C1-C4alkoxy C1-C4alkyl, C1-C6haloalkoxy, C1-C6alkylthio, C1-C6alkylsulfinyl, C1-C6alkylsulfonyl, C1-C6haloalkylthio, C1-C6haloalkylsulfinyl, C1-C6haloalkylsulfonyl, C2-C6alkylcarbonyl, C2-C6alkoxycarbonyl, C2-C6 haloalkylcarbonyl, C2-C6haloalkoxycarbonyl, (C1-C6alkyl)NH, (C1-C6 alkyl)2N, (C1-C6 cycloalkyl)NH, (C1-C6cycloalkyl)2N, C1-C6alkylcarbonylamino, C1-C6cycloalkylcarbonylamino or —SF5;
• additionally one of R10a, R10b, R10c and R10d can be oxo;
• or
• R10a, R10b, R10c, and R10d, independently from each other, are C3-C6cycloalkyl mono- or polysubstituted by substituents selected from the group consisting of C1-C4haloalkyl, C1-C4alkyl and cyano;
• or
• R10a, R10b, R10c, and R10d, independently from each other, are phenyl which can be mono- or polysubstituted by substituents selected from the group consisting of halogen, C1-C4 haloalkyl, C1-C4alkyl, C1-C4alkoxy and cyano;
• and agrochemically acceptable salts, stereoisomers, enantiomers, tautomers and N-oxides of those compounds.