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US 10,308,593 B2Granted
Additives for fuel oils
AssigneeInfineum International Limited
InventorGraham Jackson
Life of this patent
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Abstract
A fuel oil composition comprising a major amount of a fuel oil and a minor amount of a compound being the product of the 1,4-addition reaction of (i) ammonia, a primary or secondary hydrocarbyl-substituted amine or a mixture thereof to (ii) a species containing one or more α,β-unsaturated carbonyl groups, wherein the compound includes at least one hydrocarbyl group containing at least 10 carbon atoms. The fuel oil composition has improved low temperature properties.
Claims15
A fuel oil composition comprising (a) a major amount of a fuel oil;
- and (b) 10-500 ppm by weight based on the weight of the fuel oil of a compound being the product of the 1,4-addition reaction of (i) ammonia, a primary or secondary hydrocarbyl-substituted amine or a mixture thereof to (ii) a species containing one or more α,β-unsaturated carbonyl groups, wherein the compound includes at least one hydrocarbyl group containing at least 10 carbon atoms;
- and
- wherein species (ii) is of formula A-B,
- wherein A comprises a moiety of general formula I which is bonded to B via the carbonyl group:
- wherein R3 represents hydrogen, C1 to C8 hydrocarbyl group, or C(O)OR5,
- wherein R4 represents C1 to C8 hydrocarbyl group, or —C(O)OR5, where R5 represents a hydrocarbyl group, containing from 1 to 40 carbon atoms,
- wherein B independently represents —NR6R7 or —OR8,
- wherein R6 and R7 each independently represent hydrogen or a hydrocarbyl group, containing up to 40 carbon atoms which group is optionally substituted or terminated with one or more substituents selected from —OR9, —NR10R11, or a combination thereof, and/or interrupted by one or more oxygen atoms and/or —N(R12)— groups, where R9, R10, R11 and R12 each independently represent hydrogen, a hydrocarbyl group containing up to 20 carbon atoms, or a moiety of general formula I;
- and,
- wherein R8 independently represents hydrogen or a hydrocarbyl group, containing up to 40 carbon atoms which group is optionally substituted or terminated with one or more substituents of —NR14R15, and/or interrupted by one or more —N(R16)— groups, where R14, R15 and R16 each independently represent hydrogen, a hydrocarbyl group containing up to 20 carbon atoms, or a moiety of general formula I as defined herein.
7 more elements
A fuel oil composition comprising (a) a major amount of a fuel oil;
- and (b) 10-500 ppm by weight based on the weight of the fuel oil of a compound being the product of the 1,4-addition reaction of (i) an amine represented by the formula NHR1R2, where R1 and R2 each independently represent hydrogen or a hydrocarbyl group which group is optionally terminated with one or more substituents selected from —OH or —NH2 and/or interrupted by one or more oxygen atoms or —N(H)— groups to (ii) a species represented by general formula Ill
- wherein R3 represents hydrogen or a C1 to C8 hydrocarbyl group, wherein R4 represents —C(O)OR5, where R5 and R8 independently represent a hydrocarbyl group containing from 1 to 40 carbon atoms.
Dependencies are inferred from the claim text.