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US 10,246,655 B1Granted
High density renewable fuels from santalenes
AssigneeThe United States of America as represented by the Secretary of the Navy
InventorBenjamin G Harvey
Life of this patent
Estimating the term…
Abstract
A process for making high density fuels having the potential to increase the range and/or loiter time of Navy platforms. Derivation of these fuels from a sustainable source will decrease the carbon footprint of the Department of Defense (DoD) and reduce reliance on nonsustainable petroleum sources. Fuels based on santalenes have volumetric energy densities greater than JP-5 and F-76 and can be produced from biomass sugars.
Claims14
A method for manufacturing turbine and diesel fuels, comprising:
- providing a sesquiterpene mixture consisting of santalene, alpha-santalene, beta-santalene, alpha-bergamotene, farnesene, and combinations thereof, wherein the sesquiterpene mixture is generated by metabolically engineered organisms from substrates including glucose, sucrose, fructose, other reducing sugars, cellobiose, cellulose, hemicellulose, lignocellulose, lignin, methane, natural gas, and CO2, or by isolating from plant material by solvent extraction or steam distillation;
- purifying said sesquiterpene mixture, thereby forming a purified sesquiterpene mixture;
- isomerizing said purified sesquiterpene mixture with at least one heterogeneous or homogenous acid catalyst to produce isomers;
- and
- hydrogenating said isomers with at least one hydrogenation catalyst under hydrogen pressure to generate hydrogenated isomers;
- and distilling said hydrogenated isomers to produce a first high density fuel and a higher molecular weight residue.
3 more elements
A method for manufacturing turbine and diesel fuels, comprising:
- providing a sesquiterpene mixture consisting of santalene, alpha-santalene, beta-santalene, alpha-bergamotene, farnesene, and combinations thereof, wherein the sesquiterpene mixture is generated by metabolically engineered organisms from substrates including glucose, sucrose, fructose, other reducing sugars, cellobiose, cellulose, hemicellulose, lignocellulose, lignin, methane, natural gas, and CO2, or by isolating from plant material by solvent extraction or steam distillation;
- purifying said sesquiterpene mixture, thereby forming a purified sesquiterpene mixture;
- isomerizing said purified sesquiterpene mixture with at least one heterogeneous or homogenous acid catalyst to produce isomers;
- hydrogenating said isomers with at least one hydrogenation catalyst under hydrogen pressure to generate hydrogenated isomers;
- and distilling said hydrogenated isomers to produce a first high density fuel and a higher molecular weight residue;
- and
- further isomerizing said hydrogenated isomers with at least one Lewis acid catalyst to generate a hydrocarbon mixture having adamantanes and distilling the adamantane mixture to produce a second high density fuel mixture and a higher molecular weight residue.
4 more elements
Dependencies are inferred from the claim text.