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US 10,246,606 B2Granted
Transparent flexible hard coated film and method of producing the same
AssigneeKorea Advanced Institute of Science and Technology
InventorsByeong-Soo Bae, Gwang-Mun Choi, Ji-Hoon Ko
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Abstract
The invention relates to a transparent flexible hard coated film and a method of producing the same, and more particularly, to a transparent flexible hard coated film including a scratch-resistant surface and a method of producing the same.
Claims9
An ionic polymerizable siloxane hard coating composition for forming a transparent flexible hard coated film, the composition comprising:
- oligosiloxane [component (A)] having on average at least one alicyclic epoxy group per molecule;
- a reactive diluent [component (B)] that is (3,4-epoxycyclohexyl)methyl 3,4-epoxycyclohexylcarboxylate or that has on average at least one oxetane group per molecule;
- and
- an ionic polymerization initiator [component (C)],
- wherein the ionic polymerizable siloxane hard coating composition is produced by a method including mixing the component (C) of from 0.1 part by weight to 10 parts by weight with respect to 100 parts by weight of the component (A),
- wherein the component (A) has an average unit chemical formula represented by the following Chemical Formula 1:
- (R1SiO3/2)a(R22SiO2/2)b(R33SiO1/2)c(SiO4/2)d(R4O1/2)e, [Chemical Formula 1]
- wherein in Chemical Formula 1,
- R1 is an alicyclic epoxy group, and R2 and R3 are each independently selected from the group consisting of a substitutable C1-20 alkyl group, a substitutable C2-20 alkenyl group, a substitutable C2-20 alkynyl group, and a substitutable C6-20 aryl group, a substitutable substituent in the R2, and R3 is at least one member selected from the group consisting of a C1-20 alkyl group, a C3-8 cycloalkyl group, a C1-20 alkoxy group, an amino group, an acryl group, a (meth)acryl group, halogen, an allyl group, a mercapto group, an ether group, an ester group, a carbonyl group, a carboxyl group, a vinyl group, a nitro group, a sulfone group, a hydroxyl group, a cyclobutene group, an alkyd group, an urethane group, an oxetane group, a phenyl group, and combinations thereof,
- R4 is a straight or branched C1-7 alkyl group or hydrogen,
- a is a positive number,
- b is 0 or a positive number,
- c is 0 or a positive number,
- d is 0 or a positive number,
- e is 0 or a positive number,
- (b+c+d)/a is a number of from 0 to 1,
- e/(a+b+c+d) is a number of from 0 to 0.4, and
- the alicyclic epoxy group is not a glycidyl group.
15 more elements
Dependencies are inferred from the claim text.