Picolinamides as fungicides

A composition for the control of a fungal pathogen including mixtures of at least one of the compounds of Formula I

• wherein:
• Q is
• X is hydrogen or C(O)R5;
• Y is hydrogen or C(O)R5;
• Z is N or N+→O− and W is O or S;
• R1 is hydrogen or alkyl, substituted with 0, 1 or multiple R8;
• R2 is methyl;
• R3 and R3′ are independently chosen from C2-C6 alkyl, C3-C6 cycloalkyl, aryl or heteroaryl, each optionally substituted with 0, 1 or multiple R8;
• Alternatively, R3 and R3′ may be taken together to form a 3-6 membered saturated or partially saturated carbocycle or heterocycle, optionally substituted with 0, 1 or multiple R8;
• R4 is chosen from aryl or heteroaryl, each optionally substituted with 0, 1 or multiple R8;
• R5 is chosen from alkoxy or benzyloxy, each optionally substituted with 0, 1, or multiple R8;
• R6 is chosen from hydrogen, alkoxy, or halo, each optionally substituted with 0, 1, or multiple R8;
• R7 is chosen from hydrogen, —C(O)R9, or —CH2OC(O)R9;
• R8 is chosen from hydrogen, alkyl, aryl, acyl, halo, alkenyl, alkynyl, alkoxy, cyano, or heterocyclyl, each optionally substituted with 0, 1, or multiple R10;
• R9 is chosen from alkyl, alkoxy, or aryl, each optionally substituted with 0, 1, or multiple R8;
• R10 is chosen from hydrogen, alkyl, aryl, acyl, halo, alkenyl, alkoxy, or heterocyclyl;
• R11 is chosen from hydrogen or alkyl, each substituted with 0, 1 or multiple R8;
• and
• a phytologically acceptable carrier material.