Dual cure stain resistant microsphere articles

An article comprising at least a first surface having:

• (a) a binder resin layer comprising a fluorine-containing polymer, wherein the binder resin layer has a first major surface opposite a second major surface;
• and
• (b) a plurality of microspheres partially embedded and adhered to the first major surface of the binder resin layer;
• wherein the fluorine-containing polymer is a partially fluorinated polymer derived from at least one fluorine containing monomer and two or more non-fluorinated monomers having at least one active hydrogen functional group, and further wherein at least one but not all of the active hydrogen functional groups are reacted with at least one curing agent having latent functionality and wherein the partially fluorinated polymer comprises a copolymer of the structure of Formula (I):
• RfRXRLRG (I)
• wherein Rf must be present as 30 mol % to 60 mol % of the polymer, and wherein RX must be present as 5 mol % to 20 mol % of the polymer, and further wherein the remaining mol % of the polymer are RL, and RG,
• (a) Rf is selected from at least one of the following or combinations thereof:
• —CF2CF2—,
• —CFClCF2—,
• —CH2CF2—
• wherein Rf2 is fluoroalkyl having 1 to 8 carbon atoms;
• (b) RX is:
• wherein Q1 is
• or
• —O—Z—X
• wherein Z is optional, or when present, is selected from an alkylene, arylene, aralkylene or alkarylene, in which any are optionally substituted with N, O or S;
• and wherein X is OH, or SH, or NHR1, where R1 is H, alkyl or cycloalkyl having 1 to 22 carbon atoms;
• (c) RL is
• wherein Q2 is,
• or,
• —O—Z-L
• wherein Z is optional, or when present, is selected from an alkylene, arylene, aralkylene, or alkarylene, in which any are optionally substituted with N, O or S and
• L is
• or
• —Y—ZA)n,
• wherein Y is O, S, NR1, wherein R1 is H, or alkyl or cycloalkyl having 1 to 22 carbon atoms, and
• A is
• wherein n is 1 to 5 and R2 is H or CH3;
• and
• (d) RG is
• wherein Q3 is
• or
• —O—Z-G
• wherein Z is optional, or when present is selected from an alkylene, arylene, aralkylene, or alkarylene in which any are optionally substituted with N, O or S and wherein G is aryl, alkyl, aralkyl or alkaryl.