Positive electrode active material for lithium-ion battery, a positive electrode for lithium-ion battery, and lithium-ion battery
AssigneeJX Nippon Mining & Metals Corporation
InventorsShunsuke Kobayashi, Yoshio Kajiya
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Abstract
The present invention provides a positive electrode active material for lithium ion batteries having excellent battery property. The positive electrode active material for lithium ion batteries is represented by composition formula: LixNi1−yMyO2+α, wherein M is Co as an essential component and at least one species selected from a group consisting of Sc, Ti, V, Cr, Mn, Fe, Cu, Zn, Ga, Ge, Al, Bi, Sn, Mg, Ca, B and Zr, 0.9≤x≤1.2, 0<y≤0.7, α>0.05, and an average particle size (D50) is 5 μm to 15 μm.
Claims6
A manufacturing method for a positive electrode active material for lithium ion batteries, represented by composition formula:
- LixNi1−yMyO2+α, wherein
- M is Co as an essential component and at least one species selected from a group consisting of Sc, Ti, V, Cr, Mn, Fe, Cu, Zn, Ga, Ge, Al, Bi, Sn, Mg, Ca, B and Zr, 0.9≤x≤1.2, 0<y≤0.7, α>0.05, and
- an average particle size (D50) is 5 μm to 15 μm,
- comprising the steps of (1) to (5):
- (1) producing metal salt solution of Ni and at least one species selected from a group consisting of Sc, Ti, V, Cr, Mn, Fe, Co, Cu, Zn, Ga, Ge, Al, Bi, Sn, Mg, Ca, B and Zr,
- (2) suspending lithium carbonate in pure water, and then pouring the metal salt solution in the water to produce metal carbonate solution slurry,
- (3) filtering the metal carbonate solution slurry to produce a filtered lithium-containing carbonate, and then drying the lithium-containing carbonate to produce powders of a precursor for positive electrode active material for lithium ion batteries,
- (4) classifying the powders of a precursor for positive electrode active material for lithium ion batteries to produce powders having a particle size of 1 μm to 30 μm, and
- (5) conducting a calcination of the powders of a precursor for positive electrode active material for lithium ion batteries having a particle size of 1 μm to 30 μm to produce a positive electrode active material for lithium ion batteries.
Dependencies are inferred from the claim text.