Back to results
US 10,119,022 B2Granted
Polycarbonate resin composition
AssigneeIdemitsu Kosan Co., Ltd.
InventorsYoshio Okamoto, Tsuyoshi Murakami
Life of this patent
Estimating the term…
Abstract
Provided is a polycarbonate resin composition, including: a polycarbonate resin (A) containing a polycarbonate-polyorganosiloxane copolymer (A-1) having a specific structure; a copolymer (B) having constituent units derived from acrylonitrile and styrene, and being free of a constituent unit derived from methyl methacrylate; a copolymer (C) having constituent units derived from butadiene and methyl methacrylate; and a flame retardant (D), the resin composition satisfying a predetermined expression (a).
Claims13
A polycarbonate resin composition, comprising:
- (A) a polycarbonate resin (A) comprising a polycarbonate-polyorganosiloxane copolymer (A-1) having a polycarbonate block comprising a repeating unit represented by the general formula (I) and a polyorganosiloxane block comprising a repeating unit represented by the general formula (II):
- (B) a copolymer (B) having constituent units derived from acrylonitrile and styrene, and being free of a constituent unit derived from methyl methacrylate;
- (C) a copolymer (C) having constituent units derived from butadiene and methyl methacrylate;
- and
- (D) a flame retardant (D),
- wherein:
- a content of the polyorganosiloxane block comprising the repeating unit represented by the general formula (II) ranges from 0.70 mass % to 10 mass %, based on a total mass of the polycarbonate resin composition;
- the polycarbonate resin composition satisfies the expression (a):
- (Sf−37)×Ch/(Bd+Si)≥37 (a)
- Sf represents a flow length (cm) when the resin composition is molded with a spiral flow mold having a cylinder temperature of 240° C., a mold temperature of 40° C., and a thickness of 2.0 mm at a pressure setting of 125 MPa;
- Ch represents a Charpy impact strength (kJ/m2) at a temperature of 23° C. when the resin composition is molded into a molded body having a thickness of 4 mm;
- Bd represents a content (mass %) of the constituent unit derived from butadiene in the resin composition;
- Si represents a content (mass %) of the polyorganosiloxane block moiety in the resin composition;
- R1 and R2 each independently represent a halogen atom, an alkyl group having 1 to 6 carbon atoms, or an alkoxy group having 1 to 6 carbon atoms;
- X represents a single bond, an alkylene group having 1 to 8 carbon atoms, an alkylidene group having 2 to 8 carbon atoms, a cycloalkylene group having 5 to 15 carbon atoms, a cycloalkylidene group having 5 to 15 carbon atoms, a fluorenediyl group, an arylalkylene group having 7 to 15 carbon atoms, an arylalkylidene group having 7 to 15 carbon atoms, —S—, —SO—, —SO2—, —O—, or —CO—;
- R3 and R4 each independently represent a hydrogen atom, a halogen atom an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, or an aryl group having 6 to 12 carbon atoms;
- a and b each independently represent an integer of from 0 to 4;
- and
- n represents an average number of repetitions.
16 more elements
Dependencies are inferred from the claim text.