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US 10,118,977 B2Granted
Ziegler-natta catalyst and preparation thereof
AssigneeBorealis AG
InventorsVictor Sumerin, Joseph Thorman
Life of this patent
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Abstract
This invention relates to a solid MgCl2 based Natta catalyst component for producing olefin polymers and preparation of said catalyst component. Further the invention relates to a Ziegler Natta catalyst comprising said solid catalyst component, Group 13 metal compound as cocatalyst and optionally external additives. The invention further relates to the use of said catalyst component in producing olefin polymers, especially ethylene polymers with desired properties.
Claims20
A method for producing solid MgCl2 supported catalyst component comprising the steps
- a) providing solid carrier particles of MgCl2*mROH adduct;
- b) pre-treating the solid carrier particles of step a) with a compound of Group 13 metal;
- c) treating the pre-treated solid carried particles of step b) with a transition metal compound of Group 4 to 6;
- d) recovering the solid catalyst component;
- wherein the solid carrier particles are contacted with an internal organic compound of formula (I) or isomers or mixtures therefrom before treating the solid carrier particles in step c)
- wherein in the formula (I)
- R1 to R5 are the same or different and are hydrogen, a linear or branched C1 to C8-alkyl group, or a C3-C8-alkylene group, or two or more of R1 to R5 can form a ring, the two oxygen-containing rings are individually saturated or partially unsaturated or unsaturated, and R in the adduct MgCl2*mROH is a linear or branched alkyl group with 1 to 12 C atoms, and m is 0 to 6;
- and
- wherein the solid catalyst component has Mg/Ti mol/mol ratio of 1 to 10, Al/Ti mol/mol ratio of 0.01 to 1, and Cl/Ti mol/mol ratio of 5 to 20.
6 more elements
Dependencies are inferred from the claim text.