Curable polyester polyols and their use in thermosetting soft feel coating formulations
AssigneeEastman Chemical Company
InventorsJianhui Zhou, Leslie Taylor Baker
Life of this patent
Estimating the term…
Abstract
A soft feel curable polyester composition comprising the residues of a 2,2,4,4-tetraalkylcyclobutane-1,3-diol, a C2-C20 diol other than 2,2,4,4-tetraalkylcyclobutane-1,3-diol, a C2-C20 polyol, an alicyclic diacid and an acyclic aliphatic diacid, wherein said curable polyester contains at least 90 mole percent of aliphatic diacid residues, based on the total moles of diacid residues, and wherein said curable polyester has a hydroxyl number of about 100 to about 250 mgKOH/g, an acid number of 0 to about 30 mgKOH/g, and a number average molecular weight of about 500 to about 10,000 g/mole, a soft segment polyol, an isocyanate crosslinker and a solvent or a solvent mixture.
Claims17
A curable coating composition comprising:
- A) a curable aliphatic polyester composition comprising the residues of:
- i. a hydroxyl component, said hydroxyl component comprising the residues of:
- a) from 30 to about 90 mole %, based on the total moles of a) and b) of 2,2,4,4-tetraalkylcyclobutane-1,3-diol represented by the structure
- wherein R1, R2, R3, and R4 each independently are C1 to C8 alkyls;
- b) from 10 to 70 mole % based on the total moles of a) and b) of a C2-C20 diol other than 2,2,4,4-tetraalkylcyclobutane-1,3-diol;
- c) from 5 to 60 mole %, based on the total moles of a), b) and c) of a C2-C20 polyol;
- ii. a diacid component, said diacid component comprising the residues of:
- d) from 70 to about 100 mole %, based on the total moles of d) and e) of an alicyclic diacid;
- and
- e) from 0 to 30 mole %, based on the total moles of d) and e) of an acyclic aliphatic diacid;
- and
- wherein said curable polyester contains at least 90 mole percent of aliphatic diacid residues, based on the total moles of diacid residues, and wherein said curable polyester has a hydroxyl number of about 100 to about 250 mgKOH/g, an acid number of 0 to about 30 mgKOH/g, and a number average molecular weight of about 500 to about 10,000 g/mole;
- B) a polyol selected from polycarbonate diol, polytetramethylene glycol, or polycaprolactone;
- C) a crosslinker;
- and
- D) a solvent;
- wherein said curable polyester (A) is present in an amount from 10 to 50 weight %;
- said polyol (B) is present in an amount of from 50 to 90 weight %, said crosslinker (C) is present in an amount of from 10 to 50 weight % based on the total weight of said polyester (A), said polyol (B) and said crosslinker (C) in said coating composition.
Dependencies are inferred from the claim text.