Imaging processes
AssigneeXerox Corporation
InventorsRichard P. N. Veregin, Eric Rotberg, Edward Graham Zwartz, Suxia Yang, Daryl W. Vanbesien, Cuong Vong, Karen Ann Moffat
Life of this patent
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Abstract
The present disclosure provides processes for producing images with toner particles. In embodiments, toner particles of a certain diameter in size are applied to a substrate as an incomplete monolayer, and then fused to form an image that is a complete monolayer and possesses a thickness less than the diameter of the particles utilized to form the image.
Claims43
A toner comprising low melt emulsion aggregation toner particles having a core and a shell, wherein the emulsion aggregation toner particles comprise:
- a combination of amorphous polyester resins comprising a first amorphous polyester resin and second amorphous polyester resin, the first amorphous polyester resin comprising dodecenylsuccinic acid, the first and second amorphous polyester resins each having a number average molecular weight (Mn) of from about 2,000 to about 8,000, the combination of amorphous polyester resins having a melt viscosity of from about 10 to about 1,000,000 Pa*S at about 130° C;
- a low molecular weight amorphous polyester resin which exhibits a glass transition temperature of from about 30° C. to about 120° C. and having a number average molecular weight (Mn) of from about 2,000 to about 8,000, the low molecular weight amorphous polyester resin comprises a combination of low molecular weight amorphous polyester resins, wherein the at least one of the amorphous polyester resin resins is present in an amount of from about 30% to about 45% by weight of the emulsion aggregation toner particles, and further wherein the combined amorphous polyester resins have a melt viscosity of from about 10 to about 1,000,000 Pa*S at about 130° C.;
- a crystalline polyester resin which exhibits a melting temperature of from about 50° C. to about 90° C.;
- and
- a pigment colorant present in an amount of from about 7% to about 40% by weight of the toner;
- wherein the emulsion aggregation toner particles have a volume average particle diameter of about 2 μm to about 7 μm;
- further wherein the toner possesses a toner charge per mass ratio (Q/m) of from about −3 ρC μC/gram to about −90 ρC μC/gram.
A toner comprising emulsion aggregation toner particles having a core and a shell, wherein the emulsion aggregation toner particles comprise:
- a combination of amorphous polyester resins comprising a first amorphous polyester resin and a second amorphous polyester resin, the first amorphous polyester resin comprising trimellitic acid, the first and second amorphous polyester resins each having a number average molecular weight (Mn) of from about 2,000 to about 8,000, the combination of amorphous polyester resins having a melt viscosity of from about 10 to about 1,000,000 Pa*S at about 130° C. and a glass transition temperature of from about 30° C. to about 80° C.;
- wherein at least one of the first and second amorphous polyester resins is present in an amount of from about 30% to about 45% by weight of the emulsion aggregation toner particles;
- a crystalline polyester resin which exhibits a melting temperature of from about 50° C. to about 90° C.;
- wherein the crystalline polyester resin is present in an amount of from 1% to about 15% by weight of the emulsion aggregation toner particles;
- and
- a colorant present in an amount of from about 7% to about 40% by weight of the toner;
- wherein the emulsion aggregation toner particles have a volume average particle diameter of about 4 μm to about 6 μm, and
- wherein the toner possesses a toner charge per mass ratio (Q/m) of from about −3 μC/gram to about −90 μC/gram.
A toner comprising emulsion aggregation toner particles having a core and a shell, wherein the emulsion aggregation toner particles comprise:
- a combination of amorphous polyester resins comprising a first amorphous polyester resin and a second amorphous polyester resin, the first amorphous polyester resin comprising dodecenylsuccinic acid, the second amorphous polyester resin comprising trimellitic acid, the first and second amorphous polyester resins each having a number average molecular weight (Mn) of from about 2,000 to about 8,000, the combination of amorphous polyester resins having a melt viscosity of from about 10 to about 1,000,000 Pa*S at about 130° C. and a glass transition temperature of from about 30° C. to about 80° C.;
- wherein the second amorphous polyester resins is present in an amount of from about 35% to about 45% by weight of the emulsion aggregation toner particles;
- a crystalline polyester resin which exhibits a melting temperature of from about 50° C. to about 90° C.;
- and
- a colorant present in an amount of from about 7% to about 40% by weight of the toner;
- wherein the emulsion aggregation toner particles have a volume average particle diameter of about 2 μm to about 7 μm, and the toner possesses a toner charge per mass ratio (Q/m) of from about −3 μC/gram to about −90 μC/gram.
Dependencies are inferred from the claim text.