Shelf stable fast-core aqueous coating
AssigneeRohm and Haas Company
InventorsFrancis Joseph Landy, Andrew Mercurio, Roy Wesley Flynn
Life of this patent
Estimating the term…
Abstract
A shelf-stable fast-cure aqueous coating is disclosed. The coating contains an anionically stabilized latex, a polyfunctional amine and a volatile base in an amount sufficient to deprotonate the conjugate acid of the amine.
Claims27
A shelf-stable fast-cure aqueous coating composition consisting essentially of:
- (a) an anionically stabilized emulsion polymer having a Tg greater than about 0.degree. C.;
- (b) a water soluble polyfunctional amine polymer having from about 20% to about 100% of the monomer units by weight containing an amine group and having no acid groups other than trace amounts;
- and
- (c) an amount of volatile base sufficient to raise the pH of the composition to a point where essentially all of the polyfunctional amine is in a non-ionic state , a test film of said composition having a dry time of 10 minutes as determined under a modified ASTM D1640 dry test .
A shelf stable fast-cure aqueous traffic paint consisting essentially of:
- (a) an anionically stabilized emulsion polymer having a Tg greater than about 0.degree. C.;
- (b) a water soluble polyfunctional amine polymer;
- and
- (c) an amount of volatile base sufficient to raise the pH of the composition to a point where essentially all of the polyfunctional amine is in a non-ionic state , a test film of said composition having a dry time of 10 minutes as determined under a modified ASTM D1640 dry test .
A shelf stable fast-cure aqueous paint composition consisting essentially of:
- (a) an anionically stabilized emulsion polymer having a Tg greater than about 0.degree. C.;
- (b) a water soluble polyfunctional amine;
- and
- (c) an amount of a volatile base sufficient to raise the pH of the composition to a point where essentially all of said polyfunctional amine is in a non-ionic state , a test film of said composition having a dry time of 10 minutes as determined under a modified ASTM D1640 dry test .
An exterior shelf-stable fast-cure aqueous paint composition consisting essentially of:
- (a) an anionically stabilized emulsion polymer having a Tg greater than about 0.degree. C.;
- (b) 0.6 to 2.5 parts per 100 parts of emulsion solids by weight of a water soluble polyfunctional amine polymer having no acid groups other than trace amounts and polymerized from oxazolidinoethylmethacrylate monomer units;
- and
- (c) an amount of a volatile base sufficient to raise the pH of the composition to a point where essentially all of said polyfunctional amine is in a non-ionic state , a test film of said composition having a dry time of 10 minutes as determined under a modified ASTM D1640 dry test .
A shelf stable fast-cure aqueous traffic paint composition consisting essentially of:
- (a) an anionically stabilized emulsion polymer having a Tg greater than about 0.degree. C.;
- (b) a water soluble polyfunctional amine;
- and
- (c) an amount of a volatile base sufficient to raise the pH of the composition to a point where essentially all of said polyfunctional amine is in a non-ionic state , a test film of said composition having a dry time of 10 minutes as determined under a modified ASTM D1640 dry test .
An exterior shelf-stable fast-cure aqueous traffic paint composition consisting essentially of:
- (a) an anionically stabilized emulsion polymer having a Tg greater than about 0.degree. C.;
- (b) 0.6 to 2.5 parts per 100 parts of emulsion solids by weight of a water soluble polyfunctional amine polymer polymerized from oxazolidinoethylmethacrylate monomer units;
- and
- (c) an amount of a volatile base sufficient to raise the pH of the composition to a point where essentially all of said polyfunctional amine is in a non-ionic state , a test film of said composition having a dry time of 10 minutes as determined under a modified ASTM D1640 dry test .
A shelf stable fast cure aqueous composition consisting essentially of:
- (a) an anionically stabilized emulsion polymer having a Tg greater than about 0.degree. C.;
- (b) a water soluble polyfunctional amine polymer having from about 20 percent to about 100 percent of the monomer units by weight containing an amine or imine group;
- and
- (c) an amount of volatile base sufficient to raise the pH of the composition to a point where essentially all of the polyfunctional amine polymer is in a non-ionic state a test film of said composition having a dry time of 10 minutes as determined under a modified ASTM D1640 dry
- test.
A shelf stable fast cure aqueous traffic paint consisting essentially of:
- (a) an anionically stabilized emulsion polymer having a Tg greater than about 0.degree. C.;
- (b) a water soluble polyfunctional amine polymer having from about 20 percent to about 100 percent of the monomer units by weight containing an amine or imine group;
- and
- (c) an amount of volatile base sufficient to raise the pH of the composition to a point where essentially all of the polyfunctional amine polymer is in a non-ionic state, a test film of said composition having a dry time of 10 minutes as determined under a modified ASTM D1640 dry test.
A shelf stable fast cure aqueous composition consisting essentially of:
- (a)an anionically stabilized emulsion polymer having a Tg greater than about 0.degree. C.;
- (b) a water soluble polyfunctional amine polymer polymerized from monomer units containing an imine group;
- and
- (c) an amount of volatile base sufficient to raise the pH of the composition to a point where essentially all of the polyfunctional amine
- polymer is in a non-ionic state.
A shelf stable fast cure aqueous traffic paint consisting essentially of:
- (a) an anionically stabilized emulsion polymer having a Tg greater than about 0.degree. C.;
- (b) a water soluble polyfunctional amine polymer polymerized from monomer units containing an imine group;
- and
- (c) an amount of volatile base sufficient to raise the pH of the composition to a point where essentially all of the polyfunctional amine polymer is in a non-ionic state.
Dependencies are inferred from the claim text.