Polyolefin composition having high impact resistance and high temperature flow resistance
AssigneeBethlehem Steel Corporation
InventorArmand E. Brachman
Life of this patent
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Abstract
A polyolefin composition having a high level of impact resistance and high temperature flow resistance comprising 30 to 90 weight percent resin containing greater than 50 to less than 75 weight percent of polyolefin and greater than 25 to less than 50 weight percent elastomer, and 10 to 70 weight percent filler.
Claims19
[1. As a new composition of matter, a resin blend of polyolefin and an elastomer to which a filler is added characterized by having rigidity, a high level of impace resistance and high temperature flow resistance, consisting essentially of:
- (a) about 30 to 90 weight percent of a resin containing
- (i) greater than 50 to less than 75 weight percent of at least one polyolefin selected from the group consisting of isotactic crystalline polypropylene, high density crystalline polyethylene, low density polyethylene and propylene-ethylene copolymers in which propylene is present in 85-95% by weight and which has a tensile yield elongation no greater than 20%, and
- (ii) greater than 25 to less than 50 weight percent of elastomer and
- (b) about 10 to 70 weight percent of an inorganic filler selected from the group consisting of calcium carbonate, talc, clay, silica, quartz, mica,
- and barytes.]
[2. The composition of matter of claim 1 wherein the resin is about 35 to 75 weight percent and the filler is about 25 to 65 weight percent.]
[3. The composition of matter of claim 1 wherein the resin is about 40 to 60 weight percent and the filler is about 40 to 60 weight percent.]
[4. The composition of matter of claims 1, 2 or 3 in which the polyolefin is isotactic crystalline polypropylene.]
[5. The composition of matter of claims 1, 2 or 3 in which the polyolefin is crystalline high density polyethylene.]
[6. The composition of matter of claims 1, 2 or 3 in which the polyolefin is low density polyethylene.]
[7. The composition of matter of claims 1, 2 or 3 in which the polyolefin is propylene-ethylene copolymer in which propylene is present in 85-95% by weight and which has a tensile yield elongation no greter than 20%.]
[8. The composition of matter of claims 1, 2 or 3 wherein the resin contains about 55 to 70 weight percent of the polyolefin and about 30 to 45 weight percent of the elastomer.]
[9. The composition of matter of claim 8 in which the polyolefin is isotactic crystalline polypropylene.]
[10. The composition of matter of claim 8 in which the polyolefin is crystalline high density polyethylene.]
[11. The composition of matter of claim 8 in which the polyolefin is low
- density polyethylene.]
[12. The composition of matter of claim 8 in which the polyolefin is propylene-ethylene copolymer in which propylene is present in 85-95% by weight and which has a tensile yield elongation no greater than 20%.]
[13. A method for making a metal-plastic laminate with a core material having a high level of impact resistance and high temperature flow resistance comprising sandwiching between two pieces of metal sheet a plastic sheet of the composition of matter of claim 1.]
- A metal-plastic laminate containing a core material [of the composition of matter of claim 1] sandwiched between two metal sheets, the core material being characterized by a high level of impact resistance and high temperature flow resistance and being a resin blend of a polyolefin and an elastomer to which a filler is added consisting essentially of:
- (a) about 30 to 90 weight percent of a resin containing
- (i) greater than 50 to less than 75 weight percent of at least one polyolefin selected from the group consisting of isotactic crystalline polypropylene, high density crystalline polyethylene, low density polyethylene and propylene-ethylene copolymer in which propylene is present in 85-95% by weight and which has a tensile yield elongation greater than 20%, and
- (ii) greater than 25 to less than 50 weight percent of elastomer and
- (b) about 10 to 70 weight percent of an inorganic filler. 15. The [invention] metal-plastic laminate of claim [13 or]
- 14 in which the metal [is] sheets are steel. 16. The [invention] metal-plastic laminate of claim 15 [wherein] in which the polyolefin is isotactic
- crystalline polypropylene. 17. The [invention] metal-plastic laminate of claim 15 in which the polyolefin is crystalline high
- density polyethylene. 18. The [invention] metal-plastic laminate of claim 15 in which the polyolefin is low density polyethylene.
- 9. The [invention] metal-plastic laminate of claim 15 in which the polyolefin is propylene-ethylene copolymer in which the propylene is present in 85-95% by weight and has a tensile yield
- elongation no greater than 20%. 20. The [invention] metal-plastic laminate of claim 16 wherein the elastomer is
- a propylene-ethylene-diene terpolymer. 21. The [invention ] metal-plastic laminate of claim 20 wherein the resin portion comprises 70 percent by weight isotactic crystalline polypropylene and 30 percent by weight propylene-ethylene-diene terpolymer.
The metal-plastic laminate of claim 14 wherein the resin is about 35 to 75 weight percent and the filler is about 25 to 65 weight percent.
The metal-plastic laminate of claim 14 wherein the resin is about 40 to 60 weight percent and the filler is about 40 to 60 weight percent.
The metal-plastic laminate of claims 14, 15 or 16 wherein the resin contains about 55 to 70 weight percent of the polyolefin and about 30 to 45 weight percent of the elastomer.
Dependencies are inferred from the claim text.