Compositions for surface treatments

A composition comprising;

• a) at least a first compound of Formula A, and
• b) a second compound of Formula B
• X-(L3)p-Rf
• in which
• p is either 0 or 1;
• Rf is a perfluorinated aliphatic structure, branched, linear or cyclic, in which no more than six fluorine bearing carbons are connected in any single straight chain segment, this structure optionally being interrupted by one or more oxygen atoms;
• X being either:
• i) a moiety containing at least one group providing binding functionality to a surface to be treated, or containing at least one polymerisable double bond, or containing at least one cross-linkable group;
• or
• ii) an acrylate, a methacrylate, or a vinyl group;
• L3 is either:
• i) a divalent linking radical which does not form polar interactions or hydrogen bonds, or
• ii) a divalent linear or branched alkyl chain of up to six carbon atoms,
• wherein the compounds of Formula A are selected from the group consisting of:
• a) N-methyl-N-[(2-methylpropenoyl) ethyl]-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylsulfonamide;
• b) N-methyl-N-[(propenoyl)ethyl]-3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylsulfonamide;
• c) propenoic acid, 4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-2-hydroxy nonylester;
• d) 2-Methylpropenoic acid, 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-2-hydroxy nonylester;
• e) 2-(2-methylpropenoy)ethyl-2-(poly[oxy(hexafluoropropene)])-tetrafluoropropanoate;
• f) 2-(Propenoy)ethyl-2-(poly[oxy(hexafluoropropene)])-tetrafluoropropanoate;
• g) 2-Methylpropenoic acid, 4,4,5,5,6,6,7,7,8,9,9,9-dodecafluoro-2-hydroxy-8-(trifluoromethyl)-nonyl ester;
• h) Propenoic acid, 4,4,5,5,6,6,7,7,8,9,9,9-dodecafluoro-2-hydroxy-8-(trifluoromethyl)-nonyl ester;
• i) 2-Methylpropenoic acid, 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-(hydroxymethyl)octyl ester and
• j) Propenoic acid, 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-(hydroxymethyl)octyl ester.

A composition comprising;

• a) at least a first compound of Formula A
• X-(L1)n-R′-(L2)m-Rf
• in which
• n is either 0 or 1;
• m is either 0 or 1;
• Rf is a perfluorinated aliphatic structure, branched, linear or cyclic, in which no more than six fluorine bearing carbons are connected in any single straight chain segment, this structure optionally being interrupted by one or more oxygen atoms;
• X being either:
• i) a moiety containing at least one group providing binding functionality to a surface to be treated, or containing at least one polymerisable double bond, or containing at least one cross-linkable group;
• or
• ii) an acrylate, a methacrylate, or a vinyl group;
• R′ being either:
• (i) a divalent radical containing at least one group capable of forming polar interactions or hydrogen bonds;
• or
• (ii) —(CH2)pCH(OH)(CH2)q—, —(CH2)pCH(CH2OH)(CH2)q—, —NR1SO2—, —C(O)NR2— or —C(O)O—,
• wherein p and q are independently integers from 1 to 4, and
• R1, R2 independently represent a hydrogen atom or an alkyl group that is linear or branched, having from one to four carbon atoms;
• L1 and L2 are either:
• (i) independently divalent linking radicals which do not form polar interactions or hydrogen bonds, or
• (ii) independently divalent linear or branched alkyl chains of up to six carbon atoms,
• and
• b) a second compound of Formula B
• wherein the compound of Formula B is selected from the group consisting of 2-methylpropenoic acid, 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl ester and propenoic acid, 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl ester.