# US 9,984,852 B1 · Time-of-flight charged particle spectroscopy

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- Number: US 9,984,852 B1
- Document ID: US9984852B1
- Status: Granted
- Kind: B1
- Application number: 15/364,145
- Filed: 2016-11-29
- Published: 2018-05-31
- Granted: 2018-05-29
- Earliest claimed: 2016-11-28
- Assignees: FEI Company
- Applicants: FEI Company
- Inventors: Otger Jan Luiten; Petrus Henricus Antonius Mutsaers; Jasper Frans Mathijs van Rens; Wouter Verhoeven; Erik René Kieft
- Web page: https://patentgrep.com/patent/US9984852B1

## CPC

- H01J 37/26: Electron or ion microscopes; Electron or ion diffraction tubes
- H01J 37/05: Electron or ion-optical arrangements for separating electrons or ions according to their energy {or mass}(particle separator tubes H01J49/00)
- H01J 37/20: Means for supporting or positioning the object or the material; Means for adjusting diaphragms or lenses associated with the support
- H01J 37/244: Detectors; Associated components or circuits therefor
- H01J 2237/0437: Semiconductor substrate
- H01J 2237/2442: Energy-dispersive (Si-Li type) spectrometer
- H01J 2237/24485: Energy spectrometers
- H01J 2237/2449: Detector devices with moving charges in electric or magnetic fields
- H01J 2237/2626: Pulsed source
- H01J 2237/2802: Transmission microscopes
- H01J: ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS (spark-gaps H01T; electric arc lamps H05B31/00; particle accelerators H05H)

## Abstract

An apparatus for performing charged particle spectroscopy, comprising: A source, for producing a pulsed beam of charged particles that propagate along a beam path; A specimen holder, for holding a specimen at an irradiation position in said beam path; A detector arrangement, for performing energy-differentiated detection of charged particles that traverse said specimen, wherein, between said source and said detector arrangement, said beam path successively traverses: An energizing cavity, for applying a time-dependent accelerating field to said beam; A primary drift space; Said irradiation position; A temporal focusing cavity, for converting an energy differential in said beam into a time-of-flight differential; A secondary drift space.

## Claims

### Claim 1

An apparatus for performing charged particle spectroscopy, comprising:
a source, for producing a pulsed beam of charged particles that propagate along a beam path;
a specimen holder, for holding a specimen at an irradiation position in said beam path; and
a detector arrangement, for performing energy-differentiated detection of charged particles that traverse said specimen,
wherein between said source and said detector arrangement, said beam path successively traverses:
an energizing cavity, for applying a time-dependent accelerating field to said beam;
a primary drift space;
said irradiation position;
a temporal focusing cavity, for converting an energy differential in said beam into a time-of-flight differential; and
a secondary drift space.

### Claim 2 (depends on 1)

An apparatus according to claim 1, wherein at least one of said energizing cavity and said temporal focusing cavity comprises a TM010 cavity.

### Claim 3 (depends on 1)

An apparatus according to claim 1, wherein said detector arrangement comprises a TM110 cavity.

### Claim 4 (depends on 1)

An apparatus according to claim 1, wherein said source comprises a TM110 cavity.

### Claim 5 (depends on 1)

An apparatus according to claim 1, wherein a supplementary TM010 cavity is provided directly upstream or downstream of the temporal focusing cavity, and is configured to produce a second harmonic and reversed phase of the excitation in said temporal focus cavity.

### Claim 6 (depends on 1)

An apparatus according to claim 1, wherein said apparatus is comprised in a charged particle microscope.

### Claim 7 (depends on 6)

An apparatus according to claim 6, which is an EELS module.

### Claim 8

A method of performing charged particle spectroscopy, comprising:
using a source to produce a pulsed beam of charged particles that propagate along a beam path;
holding a specimen at an irradiation position in said beam path;
using a detector arrangement to perform energy-differentiated detection of charged particles that traverse said specimen,
upstream of said irradiation position, using an energizing cavity to apply a time-dependent accelerating field to said beam, and then passing the beam through a primary drift space; and
downstream of said irradiation position and upstream of said detector arrangement, using a temporal focusing cavity to convert an energy differential in said beam into a time-of-flight differential, and then passing the beam through a secondary drift space.

### Claim 9 (depends on 8)

A method according to claim 8, wherein:
specimen has a property that changes as a function of time; and
pulsed beam is used to assemble a temporal series of momentary spectroscopic snapshots of said specimen, thereby capturing temporal evolution of said property.

### Claim 10 (depends on 2)

An apparatus according to claim 2, wherein said detector arrangement comprises a TM110 cavity.

### Claim 11 (depends on 2)

An apparatus according to claim 2, wherein said source comprises a TM110 cavity.

### Claim 12 (depends on 3)

An apparatus according to claim 3, wherein said source comprises a TM110 cavity.

### Claim 13 (depends on 2)

An apparatus according to claim 2, wherein a supplementary TM010 cavity is provided directly upstream or downstream of the temporal focusing cavity, and is configured to produce a second harmonic and reversed phase of the excitation in said temporal focus cavity.

### Claim 14 (depends on 3)

An apparatus according to claim 3, wherein a supplementary TM010 cavity is provided directly upstream or downstream of the temporal focusing cavity, and is configured to produce a second harmonic and reversed phase of the excitation in said temporal focus cavity.

### Claim 15 (depends on 4)

An apparatus according to claim 4, wherein a supplementary TM010 cavity is provided directly upstream or downstream of the temporal focusing cavity, and is configured to produce a second harmonic and reversed phase of the excitation in said temporal focus cavity.

### Claim 16 (depends on 2)

An apparatus according to claim 2, wherein said apparatus is comprised in a charged particle microscope.

### Claim 17 (depends on 3)

An apparatus according to claim 3, wherein said apparatus is comprised in a charged particle microscope.

### Claim 18 (depends on 4)

An apparatus according to claim 4, wherein said apparatus is comprised in a charged particle microscope.

### Claim 19 (depends on 5)

An apparatus according to claim 5, wherein said apparatus is comprised in a charged particle microscope.

### Claim 20 (depends on 16)

An apparatus according to claim 16, which is an EELS module.
