Waterproof sheet and waterproof treatment
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsTakeshi Nakajima, Takashi Hagiwara, Hisaharu Yamaguchi, Masahiro Yoda, Mitsuru Tomaru
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Abstract
A waterproof sheet comprising a rubber base and a pressure-sensitive adhesive layer of silicone resin or gel thereon is applicable to the boundary between an outdoor tank and a concrete pedestal. The waterproof sheet maintains waterproofness over a long period of time and is in long-term service without degradation of physical properties.
Claims11
A waterproof structure of an outdoor tank comprising the outdoor tank, a concrete pedestal, a waterproof sheet comprising a pressure-sensitive adhesive layer, and a sealant,
- the outdoor tank resting on the concrete pedestal and the waterproof sheet being applied across an externally exposed boundary between the tank and the pedestal, with the pressure-sensitive adhesive layer of the waterproof sheet being directly attached to the tank and the pedestal without a primer,
- the sealant being a silicone sealant and applied along the outer periphery of the pressure-sensitive adhesive layer of the waterproof sheet to form a sealing layer at the outer periphery of the pressure-sensitive adhesive layer,
- wherein the waterproof sheet comprises an elastic silicone rubber base sheet having a thickness of 0.2 to 5 millimeters, said silicone rubber base sheet having a hardness of 10 to 90 on the JIS A scale, with
- the pressure-sensitive adhesive layer having a thickness of 0.3 to 3 millimeters and a bond strength to glass of 0.7 to 8 N/25 mm disposed on only one surface of said base sheet, the hardness of the pressure-sensitive adhesive layer being in a range of 1 to 40 on the Asker C hardness scale and being lower than the hardness of the rubber base, wherein the adhesive layer comprises a pressure-sensitive adhesive silicone resin or gel and being formed of a cured product of an addition cure silicone rubber composition which contains no fillers and wherein the only silicon-containing components are
- (A) 20 to 100 parts by weight of an organopolysiloxane containing at least two silicon-bonded alkenyl groups in a molecule, having the average compositional formula (1):
- R1aSiO(4-a)/2 (1)
- wherein each R1 is independently a monovalent hydrocarbon group of 1 to 10 carbon atoms or a C1-10 monovalent hydrocarbon group in which at least one hydrogen atom is replaced by a halogen atom or cyano radical, and a is a positive number of 1.5 to 2.8, wherein said organopolysiloxane has an average degree of polymerization of 100 to 2,000,
- (B) 0 to 80 parts by weight of a resinous copolymer predominantly comprising R3SiO1/2 units and SiO2 units, a molar ratio of R3SiO1/2 units to SiO2 units being in a range of 0.5 to 1.5, wherein R is a monovalent hydrocarbon group or a monovalent hydrocarbon group in which at least one hydrogen atom is replaced by a halogen atom or cyano radical, and R contains alkenyl in a total amount of at least 0.0001 mol/g,
- the total amount of components (A) and (B) being 100 parts by weight,
- (C) 0 to 400 parts by weight, relative to 100 parts by weight of components (A) and (B) combined, of a resinous copolymer predominantly comprising R′3SiO1/2 units and SiO2 units, a molar ratio of R′3SiO1/2 units to SiO2 units being in a range of 0.5 to 1.5, wherein R′ is a monovalent hydrocarbon group or a monovalent hydrocarbon group in which at least one hydrogen atom is replaced by a halogen atom or cyano radical, and R′ does not contain or contains alkenyl in a total amount of less than 0.0001 mol/g, in an amount of 0 to 400 parts by weight relative to 100 parts by weight of components (A) and (B) combined, the amount being such that a molar ratio of silicon-bonded hydrogen in component (D) to silicon-bonded alkenyl group in components (A), (B), and (C) is in a range of 0.32 to 0.75 when component (C) contains alkenyl,
- (D) an organohydrogenpolysiloxane containing at least two silicon-bonded hydrogen atoms in a molecule in an amount of 0.5 to 30 parts by weight relative to 100 parts by weight of components (A) and (B) combined, the amount being such that a molar ratio of silicon-bonded hydrogen in component (D) to silicon-bonded alkenyl group in components (A) and (B) is in a range of 0.2 to 1.5, and
- (E) an addition reaction catalyst in an amount which provides 0.5 to 1,000 ppm of platinum group metal based upon the total weight of components (A), (B), and (C).
A waterproof structure of an outdoor tank comprising the outdoor tank, a concrete pedestal, a waterproof sheet comprising a pressure-sensitive adhesive layer, and a sealant,
- the outdoor tank resting on the concrete pedestal and the waterproof sheet being applied across an externally exposed boundary between the tank and the pedestal, with the pressure-sensitive adhesive layer of the waterproof sheet being directly attached to the tank and the pedestal without a primer,
- the sealant being a silicone sealant and applied along the outer periphery of the pressure-sensitive adhesive layer of the waterproof sheet to form a sealing layer at the outer periphery of the pressure-sensitive adhesive layer,
- wherein the waterproof sheet comprises an elastic silicone rubber base sheet having a thickness of 0.2 to 5 millimeters, said silicone rubber base sheet having a hardness of 10 to 90 on the JIS A scale, with
- the pressure-sensitive adhesive layer having a thickness of 0.3 to 3 millimeters and a bond strength to glass of 0.7 to 8 N/25 mm disposed on only one surface of said base sheet, the hardness of the pressure-sensitive adhesive layer being in a range of 1 to 40 on the Asker C hardness scale and being lower than the hardness of the rubber base, wherein the adhesive layer comprises a pressure-sensitive adhesive silicone resin or gel and being formed of a cured product of an addition cure silicone rubber composition consisting of
- (A) 20 to 100 parts by weight of an organopolysiloxane containing at least two silicon-bonded alkenyl groups in a molecule, having the average compositional formula (1):
- R1aSiO(4-a)/2 (1)
- wherein each R1 is independently a monovalent hydrocarbon group of 1 to 10 carbon atoms or a C1-10 monovalent hydrocarbon group in which at least one hydrogen atom is replaced by a halogen atom or cyano radical, and a is a positive number of 1.5 to 2.8, wherein said organopolysiloxane has an average degree of polymerization of 100 to 2,000,
- (B) 0 to 80 parts by weight of a resinous copolymer predominantly comprising R3SiO1/2 units and SiO2 units, a molar ratio of R3SiO1/2 units to SiO2 units being in a range of 0.5 to 1.5, wherein R is a monovalent hydrocarbon group or a monovalent hydrocarbon group in which at least one hydrogen atom is replaced by a halogen atom or cyano radical, and R contains alkenyl in a total amount of at least 0.0001 mol/g,
- the total amount of components (A) and (B) being 100 parts by weight,
- (C) 0 to 400 parts by weight, relative to 100 parts by weight of components (A) and (B) combined, of a resinous copolymer predominantly comprising R′3SiO1/2 units and SiO2 units, a molar ratio of R′3SiO1/2 units to SiO2 units being in a range of 0.5 to 1.5, wherein R′ is a monovalent hydrocarbon group or a monovalent hydrocarbon group in which at least one hydrogen atom is replaced by a halogen atom or cyano radical, and R′ does not contain or contains alkenyl in a total amount of less than 0.0001 mol/g, in an amount of 0 to 400 parts by weight relative to 100 parts by weight of components (A) and (B) combined, the amount being such that a molar ratio of silicon-bonded hydrogen in component (D) to silicon-bonded alkenyl group in components (A), (B), and (C) is in a range of 0.32 to 0.75 when component (C) contains alkenyl,
- (D) an organohydrogenpolysiloxane containing at least two silicon-bonded hydrogen atoms in a molecule in an amount of 0.5 to 30 parts by weight relative to 100 parts by weight of components (A) and (B) combined, the amount being such that a molar ratio of silicon-bonded hydrogen in component (D) to silicon-bonded alkenyl group in components (A) and (B) is in a range of 0.2 to 1.5,
- (E) an addition reaction catalyst in an amount which provides 0.5 to 1,000 ppm of platinum group metal based upon the total weight of components (A), (B), and (C), and
- optionally, a hydrosilylation reaction regulator.
Dependencies are inferred from the claim text.