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US 9,975,993 B2Granted
Silane compound containing perfluoro(poly)ether group
AssigneeDaikin Industries, Ltd.
InventorsHisashi Mitsuhashi, Takashi Nomura
Life of this patent
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Abstract
A perfluoro(poly)ether group containing silane compound of the formula (1): (Rf-PFPE)α-X—(SiQkY3-k)β (1) wherein Rf, PFPE, X, Y, Q, k, α and β are as defined herein, and which is able to from a layer having water-repellency, oil-repellency and antifouling property as well as high surface slip property and high friction durability.
Claims36
A perfluoro(poly)ether group containing silane compound of the formula (1):
- (Rf-PFPE)α—X—(SiQkY3-k)β (1)
- wherein:
- Rf represents, each independently at each occurrence, a C1-16 alkyl which may be substituted by one or more fluorine atoms;
- PFPE represents —(OC4F8)a—(OC3F6)b—(OC2F4)c—(OCF2)d—
- wherein a, b, c and d are each independently an integer of 0 or more and 200 or less, the sum of a, b, c and d is 1 or more and the occurrence order of the respective repeating units in parentheses with the subscript a, b, c or d is not limited in the formula;
- X represents, each independently at each occurrence, a 3-10 valent organic group;
- Y represents, each independently at each occurrence, a hydrogen atom, a hydroxyl group, a hydrolyzable group, or a hydrocarbon group;
- with the proviso that a compound of the formula (I) wherein k=1 and all Y are an alkyl group in all units in parentheses with the subscript β is excepted;
- Q represents, each independently at each occurrence, —Z—SiR1pR23−p;
- Z represents, each independently at each occurrence, a divalent organic group:
- with the proviso that Z is not a group which forms a siloxane bond together with a Si atom present in the end of the formula (1),
- R1 represents, each independently at each occurrence, a hydroxyl group or a hydrolyzable group;
- R2 represents, each independently at each occurrence, a C1-22 alkyl group or Q′;
- Q′ has the same definition as that of Q;
- p is, each independently in each Q and Q′, an integer of 0-3, and the total sum of p is one or more in the formula (1);
- in Q, the number of Si atoms which are straightly linked via the Z group is up to five;
- k is, each independently in each unit in parentheses with the subscript β, an integer of 1-3;
- and
- α and β are, each independently, an integer of 1-9, and the sum of α and β is a valence of X.
16 more elements
Dependencies are inferred from the claim text.