Process for making biobased isoprene
AssigneesArcher Daniels Midland Company, Washington State University
InventorsJunming Sun, Changjun Liu, Yong Wang, Kevin Martin, Padmesh Venkitasubramanian
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Abstract
Processes are described for making biobased isoprene, wherein a biobased isobutene prepared from acetic acid in the presence of a catalyst is combined with a formaldehyde source to form a reaction mixture, and the reaction mixture is reacted to yield biobased isoprene. In certain embodiments, methyl-tert-butyl ether prepared by reacting the same biobased isobutene with methanol serves as a formaldehyde source, being oxidatively cracked to produce formaldehyde as well as isobutene for being converted to the biobased isoprene.
Claims11
A process for making isoprene, comprising:
- converting acetic acid to isobutene in the presence of a ZnxZryOz mixed oxide catalyst in which the ratio of x:y is from 1:100 to 10:1 and z is a stoichiometric integer for the mixed oxide catalyst;
- and
- reacting the isobutene with formaldehyde.
A process for making isoprene, comprising:
- converting acetic acid to isobutene in the presence of a ZnxZryOz mixed oxide catalyst in which the ratio of x:y is from 1:100 to 10:1 and z is a stoichiometric integer for the mixed oxide catalyst;
- reacting the isobutene with methanol to form biobased MTBE;
- oxidatively cracking at least a portion of the biobased MTBE from acetic acid to produce isobutene and formaldehyde;
- and
- reacting the isobutene and formaldehyde to form biobased isoprene.
Dependencies are inferred from the claim text.