Method to manufacture PLA using a new polymerization catalyst
AssigneePurac Biochem B.V.
InventorsGerrit Gobius Du Sart, Matthew Gwilym Davidson, Christopher James Chuck
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AssigneePurac Biochem B.V.
InventorsGerrit Gobius Du Sart, Matthew Gwilym Davidson, Christopher James Chuck
Estimating the term…
The invention relates to a method for manufacturing polylactide, comprising the steps of mixing lactide and a metal-coordination compound as polymerization catalyst to obtain a reaction mixture, polymerizing the lactide in liquid phase at a temperature of at least 150° C. to form polylactide in liquid phase and allowing the polylactide to solidify, characterized in that the polymerization catalyst comprises a metal-ligand coordination compound whereby the parent ligand answers the formula (I), whereby R represents an H atom, an aliphatic group, a halide atom or a nitro group and the metal is at least one of Zr and Hf. The invented catalysts show kinetics which is comparable to the kinetics of the known Sn-octoate catalyst.
A method for manufacturing polylactide, comprising the steps of mixing lactide and a metal-coordination compound as polymerization catalyst to obtain a reaction mixture, polymerizing the lactide at a temperature of at least 150° C. to form polylactide in liquid phase and allowing the polylactide to solidify, characterized in that the polymerization catalyst comprises a metal-ligand coordination compound whereby the parent ligand answers the formula (I),
A method for manufacturing polylactide, comprising the steps of mixing lactide and a metal-coordination compound as polymerization catalyst to obtain a reaction mixture, polymerizing the lactide at a temperature of at least 150° C. to form polylactide in liquid phase and allowing the polylactide to solidify, characterized in that the polymerization catalyst comprises a metal-ligand coordination compound whereby the parent ligand answers the formula (I),
Polylactide containing a Zr-containing compound, characterized in that the amount of Zr metal originating from the compound is 1-2000 ppm and the racemization rate of the lactoyl units within the polylactide during its manufacture is less than 2%.
Dependencies are inferred from the claim text.