Catalyst for producing carbon nanotubes and carbon nanotubes produced using same
AssigneeLG Chem, Ltd.
InventorsSungJin Kim, Dong Hyun Cho, KyungYeon Kang, Seungyong Son, Jinmyung Cha, Hyungsik Jang, Seungyong Lee, Jihee Woo
Life of this patent
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Abstract
Provided is a supported catalyst for producing carbon nanotubes with a large specific surface area. The supported catalyst enables the production of carbon nanotubes with a large specific surface area in high yield. Therefore, the catalyst can be used in various fields. Also provided are carbon nanotubes produced using the supported catalyst.
Claims12
A catalyst for producing carbon nanotubes, comprising a support and a graphitization metal catalyst supported on the support and having a maximum diffraction peak at a 2θ angle of 35 to 38° in the XRD pattern recorded in the 2θ range of 10° to 80° wherein when the intensity of the maximum diffraction peak and the intensity of a diffraction peak at a 2θ angle of 17 to 22° are defined as “a” and “b”, respectively, the ratio b/a is 0.09 to 0.15,
- wherein when the intensity of a diffraction peak at a 2θ angle of 63 to 67° is defined as “c”, the ratio c/a is in a range of 0.3 to 0.5,
- wherein the graphitization metal catalyst is a multi-component metal catalyst comprising a main catalyst and an auxiliary catalyst,
- wherein the main catalyst is selected from Co, Fe, and mixtures thereof and the auxiliary catalyst is V, and
- wherein the catalyst is a supported catalyst obtained by calcining aluminum hydroxide at a primary calcination temperature of 250° C. to 500° C. to form the support, supporting a catalytic metal precursor on the support, and calcining the catalytic metal precursor supported on the support at a secondary calcination temperature of 450° C. to 800° C., the secondary calcination temperature being higher by 200 to 400° C. than the primary calcination temperature, and
- wherein the catalyst has a crystal size of 3 to 50 nm.
Dependencies are inferred from the claim text.