# US 9,882,344 B2 · Mid to far infrared diamond Raman laser systems and methods > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 9,882,344 B2 - Document ID: US9882344B2 - Status: Granted - Kind: B2 - Application number: 13/580,859 - Filed: 2011-02-24 - Published: 2013-02-21 - Granted: 2018-01-30 - Earliest claimed: 2010-02-24 - Assignees: Macquarie University - Applicants: Richard Paul Mildren - Inventors: Richard Paul Mildren - Web page: https://patentgrep.com/patent/US9882344B2 ## CPC - H01S 3/30: using scattering effects, e.g. stimulated Brillouin or Raman effects - H01S 3/094038: {End pumping} - H01S 3/094076: {Pulsed or modulated pumping (H01S3/1024 takes precedence)} - H01S 3/094084: {with pump light recycling, i.e. with reinjection of the unused pump light, e.g. by reflectors or circulators} - H01S 3/1086: {using scattering effects, e.g. Raman or Brillouin effect} - H01S 3/163: {characterised by a crystal matrix} - H01S 3/1691: {characterised by additives / sensitisers / promoters as further dopants} - H01S 2302/00: Amplification / lasing wavelength - H01S 2303/00: Pumping wavelength - H01S: DEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL ## Abstract A mid- to far-infrared solid state Raman laser system comprising a resonator cavity comprising: an input reflector adapted to be highly transmissive for light with a first wavelength in the range of about 3 to about 7.5 micrometers for admitting the first beam to the resonator cavity; and an output reflector adapted to be partially transmissive for light with a second wavelength greater than about 5.5 micrometers for resonating the second wavelength in the resonator and for outputting an output beam, the input reflector further being adapted to be highly reflective at the second wavelength for resonating the second wavelength in the resonator; and a solid state diamond Raman material located in the resonator cavity for Raman shifting the pump beam and generating the second wavelength. ## Claims ### Claim 1 A solid-state Raman laser system comprising: a pump source for generating an input beam having an infrared wavelength in the range between 3 micrometers and 7.5 micrometers, wherein the pump source is adapted to generate a pulsed pump beam comprising pump pulses at a first wavelength of intensity between about 0.1 GW/cm2 and about 60 GW/cm2 and a pulse width between about 1 ns and 100 ns; a solid-state diamond Raman material, the laser system being adapted to generate a Raman shifted output beam having an output wavelength in the range of 5.5 to 100 micrometers and being on the long wavelength side of a two-phonon absorption band in the solid-state diamond Raman material, the solid-state diamond Raman material having a nitrogen impurity content less than 10000 ppb. ### Claim 2 (depends on 1) A laser system as claimed in claim 1 wherein the output wavelength is in the range of between about 6 and about 12 micrometers. ### Claim 3 (depends on 1) A laser system as claimed in claim 1 wherein the output wavelength is in the range of between about 6 and about 8 micrometers. ### Claim 4 (depends on 1) A laser system as claimed in claim 1 wherein the first wavelength is on the short wavelength side of the two-phonon absorption band. ### Claim 5 (depends on 1) A laser system as claimed in claim 1 wherein the Raman shifted output beam is at a wavelength corresponding to a first Stokes shift in the Raman material. ### Claim 6 (depends on 1) A laser system as claimed in claim 1 wherein the pulse width is between about 1 ns and 10 ns. ### Claim 7 (depends on 1) A laser system as claimed in claim 1 wherein the input pump beam has a linewidth with a full width half maximum of less than 2 cm−1. ### Claim 8 A mid- to far-infrared solid-state Raman laser system comprising: a pump source for generating a pump beam having a first wavelength in the range of 3 micrometers to 7.5 micrometers and being a pulsed pump beam comprising pump pulses at the first wavelength of intensity between 0.1 GW/cm2 and 60 GW/cm2 and a pulse width between about 1 ns and 100 ns; a resonator cavity comprising: an input reflector adapted to be highly transmissive for light with the first wavelength for admitting the pump beam with the first wavelength into the resonator cavity; a solid-state diamond Raman material located in the resonator cavity for Raman shifting the pump beam and generating a second wavelength in the range of 5.5 to 100 micrometers and being on the long wavelength side of a two-phonon absorption band in the solid-state diamond Raman material, the solid state Raman material having a nitrogen impurity content less than 10000 ppb; and an output reflector adapted to be partially transmissive for light with the second wavelength on the long wavelength side of the two phonon-absorption band for resonating the second wavelength in the resonator without two-phonon absorption within the solid-state diamond Raman material and for outputting an output beam, the input reflector further being adapted to be highly reflective at the second wavelength for resonating the second wavelength in the resonator. ### Claim 9 (depends on 8) A system as claimed in claim 8 wherein the output reflector is between about 1% and about 80% transmissive at the second wavelength. ### Claim 10 (depends on 8) A system as claimed in claim 8 wherein the output reflector is between 20% and 50% transmissive at the second wavelength. ### Claim 11 (depends on 8) A system as claimed in claim 8 wherein the first wavelength is on the short wavelength side of the two-phonon absorption band. ### Claim 12 (depends on 8) A system as claimed in claim 8 wherein the Raman material is an undoped Raman material. ### Claim 13 (depends on 8) A system as claimed in claim 8 wherein the Raman material is either a single-crystal diamond material or an isotopically pure diamond material. ### Claim 14 (depends on 13) A system as claimed in claim 13 wherein the diamond Raman material is derived from a chemical vapour deposition fabrication process. ### Claim 15 (depends on 8) A system as claimed in claim 8 wherein the resonator cavity is a high finesse resonator cavity for light at the second wavelength, the finesse of the resonator cavity at the second wavelength being greater than 100. ### Claim 16 (depends on 8) A system as claimed in claim 8 wherein the second wavelength is either a first order Stokes wavelength, or a second order Stokes wavelength or any combination thereof. ### Claim 17 (depends on 8) A system as claimed in claim 8 wherein the laser system is a side-pumped laser system or a non-collinearly pumped laser system. ### Claim 18 (depends on 8) A laser system as claimed in claim 8 wherein the pump laser source is selected from the group of: an optical parametric oscillator, a solid state Raman-shifted thulium laser, a solid state Raman-shifted holmium laser, and a solid state Raman-shifted erbium laser. ### Claim 19 (depends on 8) A laser system as claimed in claim 8, wherein the Raman material comprises a waveguide for guiding light at the first and/or second wavelengths in the resonator cavity. ### Claim 20 (depends on 8) A laser system as claimed in claim 8 wherein the first wavelength is derived from a tunable source such that the second wavelength is tunable by tuning the first wavelength. ### Claim 21 (depends on 20) A laser system as claimed in claim 20 wherein the second wavelength is tunable through the range of about 5.5 micrometers to about 100 micrometers. ### Claim 22 (depends on 21) A laser system as claimed in claim 21 wherein the second wavelength is continuously tunable through the range of about 5.5 micrometers to about 100 micrometers. ### Claim 23 (depends on 8) A method of laser treatment using a laser system as claimed in claim 8, the method comprising: providing the pump beam at a first wavelength of about 3.47 micrometers; directing the pump beam into the resonator cavity and incident on the Raman material thereby inducing stimulated Raman scattering in the Raman material and generating the output beam with a second wavelength of about 6.45 micrometers; and directing the output beam to a selected treatment area to perform a laser treatment to the treatment area. ### Claim 24 (depends on 23) A method of laser treatment as claimed in claim 23 wherein the method is adapted for neurosurgery. ### Claim 25 (depends on 5) A laser system as claimed in claim 5 wherein the first wavelength is on the short wavelength side of the two-phonon absorption. ### Claim 26 (depends on 8) A method of remote sensing using a laser system as claimed in claim 8, the method comprising: providing the pump beam at a first wavelength in the range of 3 to 7.5 micrometers; directing the pump beam into the resonator cavity and incident on the Raman material thereby inducing stimulated Raman scattering in the Raman material and generating the output beam having a second wavelength in the range of about 5.5 micrometers to about 100 micrometers; outputting the second wavelength from the resonator cavity as an output beam; directing the output beam towards an object or into an environment where an object or environmental substance is suspected to be located; detecting backscattered radiation from the object or environmental substance; and processing the detected radiation thereby sensing the presence or absence of the object or environmental substance. ### Claim 27 A method for generating a mid- to far-infrared beam in a solid-state Raman laser system comprising: generating a pump beam having a first wavelength in the range of 3 micrometers to 7.5 micrometers and being a pulsed pump beam comprising pump pulses at the first wavelength of intensity between about 0.1 GW/cm2 and about 60 GW/cm2 and a pulse width between about 1 ns and 100 ns; providing a resonator cavity comprising: an input reflector adapted to be highly transmissive for light with the first wavelength for admitting the pump beam with the first wavelength into the resonator cavity; a solid-state diamond Raman material located in the resonator cavity for Raman shifting the pump beam and generating a second wavelength in the range of 5.5 to 100 micrometers and being on the long wavelength side of a two-phonon absorption band in the solid-state diamond Raman material; and an output reflector adapted to be partially transmissive for the second wavelength on the long wavelength side of the two-phonon absorption band for resonating the second wavelength in the resonator without two-phonon absorption within the solid-state diamond Raman material and for outputting an output beam, the input reflector further being adapted to be highly reflective at the second wavelength for resonating the second wavelength in the resonator, the solid-state diamond Raman material having a nitrogen impurity content less than 10000 ppb; directing the pump beam with the first wavelength into the resonator cavity and incident on the Raman material thereby inducing stimulated Raman scattering in the Raman material and generating the second wavelength; and outputting the output beam with the second wavelength from the resonator cavity. ### Claim 28 A mid- to far-infrared solid state Raman laser system comprising: a pump source for generating a pump beam having a first wavelength in the range of 3 micrometers to 7.5 micrometers and being a pulsed pump beam comprising pump pulses at the first wavelength of intensity between 0.1 GW/cm2 and 60 GW/cm2 and a pulse width between about 1 ns and 100 ns; a resonator cavity comprising: an input reflector adapted to be highly transmissive for light with the first wavelength for admitting the pump beam with the first wavelength into the resonator cavity; and an output reflector adapted to be partially transmissive for light with a second wavelength in the range of 5.5 to 100 micrometers for resonating the second wavelength in the resonator and for outputting an output beam, the input reflector further being adapted to be highly reflective at the second wavelength for resonating the second wavelength in the resonator; a solid-state diamond Raman material located in the resonator cavity for Raman shifting the pump beam and generating the second wavelength, the solid-state diamond Raman material having a nitrogen impurity content less than 10000 ppb; and a heat sink in thermal contact with the solid-state diamond Raman material and operable to cool the solid-state diamond Raman material to reduce two-phonon absorption therein. ### Claim 29 A method comprising the steps of: generating a pump beam for a solid-state Raman laser system comprising: a diamond Raman material and adapted to generate a Raman shifted output beam having an output wavelength in the range of 5.5 to 100 micrometers and being on the long wavelength side of a two-phonon absorption band in the solid-state diamond Raman material, the diamond Raman material having a nitrogen impurity content less than 10000 ppb, the pump beam having a first wavelength in the range of 3 micrometers to 7.5 micrometers and being a pulsed pump beam comprising pump pulses at the first wavelength of intensity between 0.1 GW/cm2 and 60 GW/cm2 and a pulse width between about 1 ns and 100 ns.