Ion-conductive fused-ring quinone polymer, electrode active material and secondary battery
AssigneesWaseda University, Nissan Chemical Industries, Ltd.
InventorsHiroyuki Nishide, Kenichi Oyaizu, Takuma Kawai, Takuji Yoshimoto
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Abstract
A ion-conductive fused-ring quinone polymer includes recurring units of formula (1) and/or (2) below wherein each X is independently a single bond or a divalent group, and A1 and A2 are each independently an aromatic hydrocarbon ring or an oxygen atom or sulfur atom-containing aromatic heterocycle that forms together with two carbon atoms on a benzoquinone skeleton. This polymer is a material having charge-storing properties which, when used as an electrode active material, is capable of providing a high-performance battery possessing high capacity, high rate characteristics and high cycle characteristics.
Claims24
An ion-conductive fused-ring quinone polymer comprising
- recurring units of formula (1) and/or (2) below
- wherein each X is independently a single bond or a divalent group, and Ar1 and Ar2 are each independently an aromatic hydrocarbon ring or an oxygen atom or sulfur atom-containing aromatic heterocycle that forms together with two carbon atoms on a benzoquinone skeleton, wherein said quinone polymer further comprises
- recurring units of formula (3) below
- wherein Y is a halogen atom.
An ion-conductive fused-ring quinone polymer comprising
- recurring units of formula (1) and/or (2) below
- wherein each X is independently a single bond or a divalent group, and Ar1 and Ar2 are each independently an aromatic hydrocarbon ring or an oxygen atom or sulfur atom-containing aromatic heterocycle that forms together with two carbon atoms on a benzoquinone skeleton, wherein said quinone polymer further comprises
- recurring units of formula (4) or (4′) below
- wherein Z is an alkoxy group of 1 to 12 carbon atoms, an alkyl group of 1 to 12 carbon atoms, an alkylthio group of 1 to 12 carbon atoms, an acyl group of 2 to 12 carbon atoms, an alkylamino group of 1 to 12 carbon atoms, a polyalkylene ether group, a polyalkyleneamine group or an aryl group;
- Z′ is —O—(CH2)a—O—, —(CH2)a—, —S—(CH2)a—S—, —C(═O)—(CH2)b—C(═O)—, —NH—(CH2)a—NH—, —O—(R—O)c—, —NH—(R—NH)c— or a phenylene group;
- R is an alkylene group of 1 to 12 carbon atoms;
- the letter a is an integer from 1 to 12, the letter b is an integer from 1 to 10, and the letter c is an integer from 2 to 4.
Dependencies are inferred from the claim text.