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US 9,868,850 B2Granted
Rubber compositions including siliceous fillers
AssigneeBridgestone Corporation
InventorsYuan-Yong Yan, Zengquan Qin, Xiao-Dong Pan
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Abstract
Vulcanizates with desirable properties can be obtained from compositions incorporating polymers that include hydroxyl group-containing aryl functionalities, silica or other particulate filler(s) that contain or include oxides of silicon and a group or compound that can act to covalently bond the filler particles and the polymer. The group can be provided as a substituent of the filler particle, or a discreet compound can be provided in the composition.
Claims13
A method of making a filled rubber composition, said method comprising
- a) providing a first composition by blending at an increasing temperature profile beginning at a temperature of at least about 120° C. and ending at a temperature of no higher than about 165° C.
- (1) a polymer that comprises
- (i) ethylenic unsaturation and
- (ii) pendent or terminal functionality which comprises an aryl group having at least two substituents defined by the formula —OR, wherein R is H or a hydrolyzable group, or an oxidation product thereof,
- (2) filler particles that comprise oxides of silicon, and
- (3) one or more compounds defined by the general formula YR1L where L is a group that contains at least one Si—O bond, R1 is a hydrocarbylene group, and Y is a functionality that comprises a —OH, —SH, —NHR2, —CN, —C(O)R2 or —NCO group in which R2 is H or a substituted or unsubstituted hydrocarbyl group;
- and
- b) in a stage involving an increasing temperature profile beginning at a temperature of at least about 90° C. and ending at a temperature of no more than 150° C., mixing said first composition with at least one sulfide-containing silane coupling agent so as to provide said filled rubber composition.
5 more elements
Dependencies are inferred from the claim text.