Polycarbonate composition having improved optical and thermal properties
AssigneeCovestro Deutschland AG
InventorsKarl-Heinz Köhler, Franky Bruynseels
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Abstract
The invention relates to aromatic polycarbonates which comprise dioxydiarylcycloalkane structural units, and which have improved optical and thermal properties. It also relates to an improved process to produce the said polycarbonates from dihydroxydiphenylcyloalkanes, and also to mixtures of these polycarbonates with polymers, with fillers, with dyes and with conventional additives.
Claims8
A process for producing a polycarbonate composition by an interfacial process or a melt transesterification process using bisphenol TMC and bisphenol A, characterized in that the sulphur content of the bisphenols used to produce the polycarbonate is less than 1.5 ppm;
- wherein the polycarbonate composition comprises at least one polycarbonate component comprising structural units of the general formula (I):
- where R1 and R2, independently of one another, are H, halogen, C1-C8-alkyl, C5-C6-cycloalkyl, C6-C10-aryl and C7-C12-arylalkyl, where m is 4 or 5, where R3 and R4 are freely selectable for each X and, independently of one another, are H or C1-C8-alkyl, where X is carbon, characterized in that the sulphur content in the composition is less than 2.0 ppm;
- wherein the at least one polycarbonate component is an aromatic polycarbonate made from 30 to 70 mol % of 3,3,5-trimethyl-1,1-bis(4-hydroxyphenyl)cyclohexane (bisphenol TMC) and 30 to 70 mol % bisphenol A, based on the total amount of bisphenols;
- and
- wherein the polycarbonate composition optionally comprises polymer additives or mixture constituents selected from the group of mould-release agents, flow aids, heat stabilizers, antioxidants, UV absorbers and/or IR absorbers, flame retardants, antistatic agents, dyes and pigments, fillers, thermoplastics or elastomers.
A method for producing transparent or translucent or opaque or coloured mouldings comprising:
- mixing bisphenol A and bisphenol TMC and optional polymer additives to form a polycarbonate composition, wherein the sulphur content in the composition is less than 1.5 ppm, and compounding and extruding them in the melt at temperatures of from 240° C. to 300° C.;
- wherein the polycarbonate composition comprises at least one polycarbonate component comprising structural units of the general formula (I):
- where R1 and R2, independently of one another, are H, halogen, C1-C8-alkyl, C5-C6-cycloalkyl, C6-C10-aryl and C7-C12-arylalkyl, where m is 4 or 5, where R3 and R4 are freely selectable for each X and, independently of one another, are H or C1-C8-alkyl, where X is carbon, characterized in that the sulphur content in the composition is less than 2.0 ppm;
- wherein the at least one polycarbonate component is an aromatic polycarbonate made from 30 to 70 mol % of 3,3,5-trimethyl-1,1-bis(4-hydroxyphenyl)cyclohexane (bisphenol TMC) and 30 to 70 mol % bisphenol A, based on the total amount of bisphenols;
- and
- wherein the polycarbonate composition optionally comprises polymer additives or mixture constituents selected from the group of mould-release agents, flow aids, heat stabilizers, antioxidants, UV absorbers and/or IR absorbers, flame retardants, antistatic agents, dyes and pigments, fillers, thermoplastics or elastomers.
Dependencies are inferred from the claim text.