Back to results
US 9,868,112 B2Granted
Fischer-Tropsch synthesis catalyst, manufacturing method therefor, and hydrocarbon manufacturing method
AssigneeJx Nippon Oil & Energy Corporation
InventorsHideki Ono, Yoshiyuki Nagayasu, Kazuaki Hayasaka
Life of this patent
Estimating the term…
Abstract
A Fischer-Tropsch synthesis catalyst containing 10 to 30% by mass, as a metal atom, of metallic cobalt and/or cobalt oxide, based on the mass of the catalyst, supported on a carrier containing silica, in which the carrier has an average pore diameter of 8 to 25 nm and the metallic cobalt and/or cobalt oxide has an average crystallite diameter of not less than the average pore diameter of the carrier and less than 35 nm.
Claims4
A method, comprising:
- loading an active metal for loading a cobalt compound on a carrier containing silica having an average pore diameter of 8 to 25 nm so that the loading amount of the cobalt compound as a cobalt atom becomes 10 to 30% by mass, based on the mass of the catalyst;
- calcining the carrier supporting the cobalt compound to obtain a catalyst precursor in which the cobalt compound is converted into cobalt oxide;
- reducing the catalyst precursor in an atmosphere containing at least molecular hydrogen to obtain a reduced catalyst precursor;
- and
- steaming the reduced catalyst precursor with a mixed gas containing 1 to 30% by volume of steam and an inert gas at a temperature of 100 to 300° C. to obtain a Fischer-Tropsch synthesis catalyst;
- wherein the Fischer-Tropsch synthesis catalyst comprises 10 to 30% by mass, as a metal atom, of metallic cobalt and/or cobalt oxide, based on the mass of the catalyst, supported on a carrier containing silica,
- the carrier has an average pore diameter of 8 to 25 nm, and
- the metallic cobalt and/or cobalt oxide has an average crystallite diameter of not less than the average pore diameter of the carrier and less than 35 nm.
5 more elements
Dependencies are inferred from the claim text.