Hydrogenated graphene with surface doping and bandgap tunability
AssigneeThe United States of America as represented by the Secretary of the Navy
InventorsJeffrey W. Baldwin, Bernard R. Matis, James S. Burgess, Felipe Bulat-Jara, Adam L. Friedman, Brian H. Houston
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Abstract
A graphene compound made from the method of preparing graphene flakes or chemical vapor deposition grown graphene films on a SiO2/Si substrate; exposing the graphene flakes or the chemical vapor deposition grown graphene film to hydrogen plasma; performing hydrogenation of the graphene; wherein the hydrogenated graphene has a majority carrier type; creating a bandgap from the hydrogenation of the graphene; applying an electric field to the hydrogenated graphene; and tuning the bandgap.
Claims3
A graphene compound made from the method of preparing graphene flakes or chemical vapor deposition grown graphene films on a SiO2/Si substrate;
- exposing the graphene flakes or the chemical vapor deposition grown graphene film to hydrogen plasma;
- performing hydrogenation of the graphene;
- wherein the hydrogenated graphene has a majority carrier type;
- creating a bandgap from the hydrogenation of the graphene;
- applying an electric field to the hydrogenated graphene;
- tuning the bandgap;
- controlling the majority carrier type via surface adsorbates;
- attaching by physisorption the surface adsorbates to the hydrogenated graphene;
- converting the majority carrier type from electrons to holes using the surface adsorbates;
- converting the majority carrier type from n-type to p-type;
- removing the surface adsorbates;
- preserving the hydrogenated graphene band structure;
- and
- converting the majority carrier type from p-type to n-type.
A graphene compound comprising hydrogenated graphene with a bandgap and exhibiting n-type nature wherein the bandgap is tunable with an electric field effect and wherein the hydrogenated graphene has a majority carrier type and a bandgap created from the hydrogenation of the graphene and
- wherein an electric field applied to the hydrogenated graphene tunes the bandgap;
- wherein the majority carrier type is controlled via surface adsorbates;
- wherein the bandgap is higher for higher hydrogen to carbon H/C ratios;
- and
- wherein the bandgap has a maximum value at the charge neutrality point (CNP).
A graphene compound comprising hydrogenated graphene with a bandgap and exhibiting n-type nature further including surface adsorbates physisorbed to the hydrogenated graphene wherein the surface adsorbates are water and results in a p-type material wherein the hydrogenated graphene is formed by the process of preparing exfoliated graphene flakes or a chemical vapor deposition (CVD) grown graphene film on a SiO2/Si substrate, depositing contact electrodes on the exfoliated graphene flakes or the CVD grown graphene films, exposing the exfoliated graphene flakes or the chemical vapor deposition grown graphene film to hydrogen plasma, hydrogenating the exfoliated graphene flakes or the CVD grown graphene films, creating a bandgap from the step of hydrogenating the graphene, applying an electric field to the hydrogenated graphene, and tuning the bandgap;
- wherein the contact electrodes are Cr/Au contact electrodes and the hydrogenating is performed with 15-30 W, 1.5 Torr H2, 100 sccm H2, 32 C, for 15-30 seconds.
Dependencies are inferred from the claim text.