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US 9,850,350 B2Granted
Block copolymer, method of producing block copolymer, and method of producing structure containing phase-separated structure
AssigneesTokyo Ohka Kogyo Co., Ltd., Tokyo Institute of Technology
InventorsTakehiro Seshimo, Teruaki Hayakawa
Life of this patent
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Abstract
A block copolymer containing a first block having a structure represented by general formula (1) shown below (Rs01 and Rs02 each independently represents an organic group, provided that at least one of Rs01 and Rs02 has a polar group; and * represents a valence bond).
Claims10
A block copolymer containing a first block consisting of structural units represented by general formula (1-1) shown below:
- wherein R represents a hydrogen atom, an alkyl group of 1 to 5 carbon atoms or a halogenated alkyl group of 1 to 5 carbon atoms;
- Ys01 represents a divalent linking group;
- Rs01a represents an organic group having a polar group selected from the group consisting of formulae (Rs01-1) to (Rs01-11) shown below:
- wherein Rs001 represents an organic group;
- and,
- and a second block selected from the group consisting of:
- a block in which structural units derived from styrene or a styrene derivative are repeatedly bonded,
- a block in which structural units derived from an acrylate ester which may have the hydrogen atom bonded to the carbon atom on the α-position substituted with a substituent are repeatedly bonded,
- a block in which structural units derived from acrylic acid which may have the hydrogen atom bonded to the carbon atom on the α-position substituted with a substituent are repeatedly bonded,
- a block in which structural units derived from an alkyleneoxide are repeatedly bonded, and
- a block in which silsesquioxane structure-containing structural units are repeatedly bonded.
8 more elements
Dependencies are inferred from the claim text.