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US 9,834,536 B2Granted
Method for producing catalyst for cyclic carbonate synthesis
AssigneesNational Institute of Advanced Industrial Science and Technology, Maruzen Petrochemical Co., Ltd.
InventorsToshikazu Takahashi, Hiroyuki Yasuda, Toshiyasu Sakakura, Shouji Yamamoto, Takashi Naniki, Takuro Furukawa
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Abstract
A method for producing a heterogeneous catalyst for use of synthesizing cyclic carbonates by reacting an epoxide and carbon dioxide in the presence of the catalyst. A method for making a catalyst that includes forming a catalyst precursor then reacting the catalyst precursor with a tertiary phosphine.
Claims10
A method for producing a catalyst, comprising:
- obtaining a catalyst precursor having a haloalkyl group or a haloaryl group, by reacting a silane compound having a haloalkyl group or a haloaryl group with a silica gel having an average pore diameter of 3.5 nm to 50 nm, and
- obtaining the catalyst, by reacting the catalyst precursor with a tertiary phosphine, at a temperature of 100-160° C. for 10-50 hours in xylene, wherein the catalyst formed by the reacting has a [halogen]/[phosphorus] molar ratio of 0.8 to 1.5,
- wherein the catalyst has a phosphorus content of 0.25 mmol to 0.6 mmol per 1 g of the catalyst,
- wherein the silane compound has formula (1):
- X—R1—Si(OR2)3 (1)
- wherein R1 represents a linear or branched alkylene group having 2 to 8 carbon atoms, an arylene group, an alkarylene group, an arylenealkylene group or an alkylenearylene group;
- R2 represents an alkyl group having 1 to 4 carbon atoms;
- and X represents a halogen atom, and
- wherein the tertiary phosphine has formula (2):
- wherein R3 to R5 each independently represents an alkyl group having 1 to 8 carbon atoms, an aryl group, an aralkyl group, an alkoxyalkyl group or an alkoxy substituted aryl group.
7 more elements
Dependencies are inferred from the claim text.