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US 9,815,799 B2Granted
Surface-modifying agent and article using same
AssigneeDexerials Corporation
InventorsMakiya Ito, Kenji Kobayashi, Nobuo Tano, Kyungsung Yun
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Abstract
Provided are a surface-modifying agent that enables production of a coating film that preserves transparency of a substrate while displaying high water repellency and excellent stain resistance, particularly in terms of wipeability of oil-based ink, and also an article for which the surface-modifying agent is used. The surface-modifying agent includes a triazine skeleton, a (meth)acrylate group bonded to the triazine skeleton via an urethane bond, and a perfluoropolyether chain bonded to the triazine skeleton.
Claims5
A surface-modifying agent comprising:
- a triazine skeleton;
- a (meth)acrylate group bonded to the triazine skeleton via an urethane bond;
- and
- a perfluoropolyether chain bonded to the triazine skeleton, wherein
- the surface-modifying agent is represented by formula (1) or (2) shown below,
- where, in the formulae (1) and (2):
- —X— represents —O—, —N(R1)—, or —O—CH2CH2—O—, wherein R1 represents hydrogen or an alkyl group;
- —Y— represents a perfluoropolyether chain selected from the group consisting of —(OCF2)n—O—(CF2CF2O)m—, —O—(CF2CF2O)p—, —O—(CF2CF2CF2O)q—, and —O—(CF(CF3)CF2C)r—, wherein m, n, p, q, and r each represent a positive integer, 0.8<m/n<3 is satisfied, and units composing —Y— may be bonded to one another in any order;
- R and R′ may represent the same or different structures each indicated by hydrogen, an alkyl group having a carbon number of 1-8, or —R2—O—CO—NH—R3, with at least one of R and R′ being a structure indicated by —R2—O—CO—NH—R3, wherein R2 represents an alkylene group having a carbon number of 2-8 and having a chain, branched, or ring shape, and R3 represents —CH2CH2—OCO—CH═CH2, —CH2CH2—OCO—C(CH3)═CH2, or —C(CH3)—(CH2—OCO—CH═CH2)2;
- and
- Z— represents CF3—, CF3—CF2—O—, CF3—CF2—CF2—, or CF3—CF(CF3)—O—.
8 more elements
Dependencies are inferred from the claim text.