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US 9,809,668 B2Granted
Polymerizable compound, composition, polymer, optically anisotropic body, liquid crystal display device, and organic EL device
AssigneeDIC Corporation
InventorsHiroshi Hasebe, Yoshio Aoki, Kunihiko Kotani, Akihiro Koiso, Hidetoshi Nakata
Life of this patent
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Abstract
It is an object of the present invention to provide a polymerizable compound suitable as a material for optically anisotropic bodies having excellent optical properties, a composition containing the polymerizable compound, a polymer obtained by polymerizing the polymerizable compound, an optically anisotropic body formed of the polymer, and a liquid crystal display device including the optically anisotropic body.
Claims9
A polymerizable compound represented by general formula (1):
- [in the formula, P represents a polymerizable functional group and Sp represents a spacer group or a single bond,
- A1, A2, A3, and A4 each independently represent a divalent alicyclic hydrocarbon group or aromatic hydrocarbon group,
- X1, X2, X3, and X4 each independently represent a divalent linking group or a single bond (at least one of X1, X2, X3, and X4 represents one of linking groups selected from —CH2CH2COO—, —CH2CH2OCO—, —COOCH2CH2—, —OCOCH2CH2—, —CH═CH—, —CH═CHCOO—, —OCOCH═CH—, —N═N—, —N═C—, and —C═N—N═C—), wherein a combination of X2 and X3 (hereafter expressed as “X2/X3”) in the general formula (1) is as follows:
- “—COO—(CH2)u—/—CH2CH2—COO—”, “—COO—(CH2)u—/—COO—CH2CH2—”,
- “—COO—(CH2)u—/—OCO—CH2CH2—”, “—COO—(CH2)u—/—CH2CH2—OCO—”,
- “—OCO—(CH2)u—/—CH2CH2—COO—”, “—OCO—(CH2)u—/—COO—CH2CH2—”,
- “—OCO—(CH2)u—/—OCO—CH2CH2—”, “—OCO—(CH2)u—/—CH2CH2—OCO—”,
- “—OCO—CH2CH2—/—COO—(CH2)u—”, “—CH2CH2—OCO—/—COO—(CH2)u—”,
- “—CH2CH2—COO—/—(CH2)u—”, “—COO—CH2CH2—/—COO—(CH2)u—”,
- “—OCO—CH2CH2—/—OCO—(CH2)u—”, “—CH2CH2—OCO—/—OCO—(CH2)u—”,
- “—CH2CH2—COO—/—OCO(CH2)u—”, “—COO—CH2CH2—/—OCO—(CH2)u—”,
- (u represents an integer of 0 to 2)
- “single bond/—CH2CH2—COO—”, “single bond/—COO—CH2CH2—”,
- “single bond/—OCO—CH2CH2—”, “single bond/—CH2CH2—OCO—”,
- “—OCO—CH2CH2—/single bond”, “—CH2CH2—OCO—/single bond”,
- “—CH2CH2—COO—/single bond”, or “—COO—CH2CH2—/single bond,”
- R1 represents an alkyl group having 1 to 12 carbon atoms, an alkoxy group having 1 to 12 carbon atoms, or “*-Sp-P” (* represents a bond with A4 or A3),
- R3 represents an alkyl group having 1 to 6 carbon atoms, an alicyclic hydrocarbon group, or an aromatic hydrocarbon group, wherein a hydrogen atom in the alicyclic hydrocarbon group or the aromatic hydrocarbon group may be substituted with an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, a halogen atom, a cyano group, a nitro group, a —C≡C—CH3 group, or a hydroxy group,
- m and n each independently represent an integer of 0 to 4 (m+n is an integer of 2 or more),
- T1 represents —S—, —O—, —CH2—, —NH—, —C(═O)—, —S(═O)—, or —C(═S)—,
- T2 represents ═CR2— or ═N—, and
- R2 represents a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, a cyano group, a nitro group, or a hydroxy group].
19 more elements
Dependencies are inferred from the claim text.