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US 9,809,657 B2Granted
Low-viscosity concentrated solutions of alkaline earth metal alkoxides in aprotic solvents and processes for preparation thereof
AssigneeAlbemarle Germany GmbH
InventorsUlrich Wietelmann, Armin Stoll, Florian Kiefer, Ute Emmel
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Abstract
A solution of a mixed alkaline earth alkoxide compound with an aluminum compound in an aprotic solvent, and methods of making and using them.
Claims11
A solution comprising a mixed alkaline earth alkoxide compound of formula M(OCH2R6)2-a-b(OR7)a[(CHR8)nOR9]b in a mixture with an aluminum compound of formula Al(OCH2R6)3-c-d(OR7)c[O(CHR8)—OR9]d in an aprotic solvent, wherein
- M is an alkaline earth metal selected from Mg, Ca, Ba, and Sr;
- OCH2R6 is an alkoxide radical composed of at least 3 and a maximum of 40 C atoms having a branch in the 2-position, relative to O;
- R7 is an alkyl radical containing 2-15 C atoms which is either linear or has a branch at the 3- or higher position relative to O;
- O(CHR8)nOR9 is an alkoxide radical in which
- R8 is an alkyl radical containing 1-6 C atoms which is either linear or has a branch at the 3- or higher position relative to O;
- R9 is an alkyl radical containing 2-15 C atoms which is either linear or has a branch;
- n is an integer between 1 and 4;
- a+b≦2;
- c+d≦3;
- a and c are from 0.01 to 0.8;
- and
- b and d each range from 0.1 to 1.99;
- and
- wherein the solution has a content of aluminum relative to the alkaline earth metal in the range between 0.2 and about 20 mol %.
11 more elements
Dependencies are inferred from the claim text.