Salts of phosphorus oxide as N-dopants for organic electronics

An organic electronic component comprising:

• a substrate;
• first and second electrodes;
• and at least one electron-conducting layer, disposed between the first and second electrodes, including a salt-type derivative of a phosphorus oxo compound having an n-dopant as follows
• where X, Y are greater than 0 and not greater than 3;
• n, m are integers greater than 0 and less than 4;
• M is a metal and R1=O1, S, Se, O—R, S—R, Se—R and R2=R, O—R, S—R, Se—R, and R is selected from the group consisting of substituted and unsubstituted alkyl, long-chain alkyl, cycloalkyl, haloalkyl, aryl, arylene, haloaryl, heteroaryl, heteroarylene, heterocycloalkylene, heterocycloalkyl, haloheteroaryl, alkenyl, haloalkenyl, alkynyl, haloalkynyl, ketoaryl, haloketoaryl, ketoheteroaryl, ketoalkyl, haloketoalkyl, ketoalkenyl, haloketoalkenyl;
• and
• wherein the salt-type derivative of a phosphorus oxo salt is one of a cesium salt and a rubidium salt of a compound selected from the group consisting of:
• 6,7,11,12,19,20,24,25-octahydrodibenzo[g,r]-[1,3,6,9,12,14,17,20,2,13]-octaoxadiphosphacyclodocosine-9,22-diol 9,22-dioxide:
• (4R)-22-hydroxy-5,5-dimethyl-4-phenyl-1,3,2-dioxaphosphorinan 2-oxide;
• 8,9-diphenyldiphenanthro[4,3-d:3,4-f][1,3,2]dioxaphosphepin-18-ol 18-oxide;
• 2,6-bis(triphenylsiyl)dinaphtho[2,1-d:1,2-f][1,3,2]dioxaphosphepin-4-ol 4-oxide;
• 1-butyl-3-methylimidazolium dibutylphosphate and corresponding di(C1-C10)alkyl derivatives;
• diphenyl hydrogenphosphate;
• bis(4-nitrophenyl) hydrogenphosphate;
• 2-naphthyl 4-[(E)-phenyldiazenyl]phenylhydrogenphosphate;
• dinaphtho[2,1-d:1,2-f][1,3,2]dioxaphosphepin-4-ol 4-oxide;
• (R)-3,3′-bis[3,5-bis(trifluoromethyl)phenyl]-1,1′-binaphthyl-2,2′-diylhydrogenphosphate;
• (S)-3,3′-bis(2,4,6-triisopropyl-phenyl)-1,1′-binaphthyl-2,2′-diylhydrogenphosphate;
• 18-hydroxy-8,9-diphenyldiphenanthro[4,3-d:3′,4′-f][1,3,2]-dioxaphosphepin 18-oxide;
• (IIbR)-4-hydroxy-2,6-bis(triphenylsilyl)dinaphtho-[2,1-d:1′,2′f]-1,3,2-dioxaphosphepin 4-oxide;
• (R)-(−)-3,3′-bis(triphenylsilyl)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate;
• lithium carbamoylphosphate;
• D-myo-inositol 1-monophosphate;
• 6-benzoyl-2-naphthyl phosphate;
• 4-nitrophenyl phosphate bis(cyclohexylammonium) salt;
• Naphthol AS phosphate;
• Naphthol AS-X phosphate;
• 4-tert-pentyl)phenyl phosphate;
• geranylgeranyl pyrophosphate;
• Naphthol AS phosphate;
• methyl phosphonate;
• trichloromethyl phosphonate;
• heptane-1,7-diyldiphosphonate;
• (heptylsulfanyl)methyl phosphonate;
• 1-hydroxybutyl phosphonate;
• 2-phenylethyl phosphonate;
• butylhydrogentrichloromethyl phosphonate;
• 4-methoxyphenyl phosphonate;
• 3-phenylpropyl phosphonate;
• dimethylallyl phosphonate;
• 1-aminopentane-1,1-diyl diphosphonate;
• 4-iodobenzyl phosphonate;
• ((2-cyanoethyl)-phosphonomethylamino)acetate;
• 4-ethoxyphenyl phosphonate;
• (+−)-2-amino-4-phosphonobutanate;
• glyphosate 3-13C[(phosphonomethyl)amino]acetate;
• amino(phenyl)methyl phosphonate;
• 3-(carboxymethylphosphonomethylamino)-propionate;
• D-(−)-2-amino-5-phosphonopentanate;
• 2-amino-7-phosphonoheptanate;
• tetramethyl 2-oxopropane-1,3-diyl diphosphonate;
• 2-methoxybenzyl phosphonate;
• tetraethylmethylene diphosphonate;
• diethyl methoxymethyl-phosphonate;
• methyl 6-[hydroxy(isopropoxy)phosphoryl]-hexanoate;
• ((2-cyanoethyl)(hydroxymethoxyphosphoryl-methyl)amino)acetate;
• dipropylchloromethylphosphonate;
• amino[4-(trifluoromethyl)phenyl]methylphosphonate;
• and [(4-chlorobenzyl)amino]methylphosphonate.