Dispersant for use in synthesis of polyaryletherketones
AssigneeTicona LLC
InventorKamlesh P. Nair
Life of this patent
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Abstract
A method for forming a polyaryletherketone is described. More particularly, a reaction mixture is initially supplied to the reactor vessel that contains one or more precursor monomers. A heteroaryl compound is also added to the reaction mixture. The reaction can be carried out according to, e.g., an electrophilic aromatic substitution reaction or a nucleophilic aromatic substitution reaction. The heteroaryl compound can serve as a dispersant to the polymer as it is formed. This minimizes the likelihood of gelling of the product polymer within the reactor vessel and limits the impact of process disruptions on the production of the polyaryletherketone.
Claims21
A method for forming a polyaryletherketone, the method comprising:
- supplying one or more monomers to a reactor vessel to form a reaction mixture, wherein the one or more monomers are precursors for the polyaryletherketone, and at least one of the one or more monomers is a halide-containing monomer;
- introducing a heteroaryl compound into the reactor vessel, wherein the heteroaryl compound has the following Formula (I):
- or a salt, derivative or adduct thereof, wherein,
- the ring is a 6-membered aromatic ring wherein A1, A2, A3, A4, A5, and A6 are each independently carbon, nitrogen or oxygen, with the proviso that at least 3 of A1, A2, A3, A4, A5, and A6 are carbon atoms, wherein each nitrogen is optionally oxidized, and wherein the ring may be optionally fused or linked to a 5- or 6-membered aryl, heteroaryl, cycloalkyl, or heterocyclyl;
- R1 is acyl, acyloxy, acylamino, alkoxy, alkenyl, alkyl, amino, aryl, aryloxy, carboxyl, carboxyl ester, cycloalkyl, cycloalkyloxy, hydroxyl, halo, haloalkyl, heteroaryl, heteroaryloxy, heterocyclyl, or heterocycyloxy;
- m is from 0 to 4;
- and
- the one or more monomers reacting with one another in the presence of the heteroaryl compound to form the polyaryletherketone.
Dependencies are inferred from the claim text.