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US 9,803,047 B2Granted
Alternating ring-opening metathesis polymerization
AssigneeThe Research Foundation for The State University of New York
InventorsNicole S. Sampson, Li Tan, Kathlyn Parker
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Abstract
The invention relates to the field of polymers and olefin polymerization, and more specifically olefin metathesis polymerization. The invention provides regioregular alternating polymers and methods of synthesizing such polymers. To demonstrate, polymers were synthesized and modified with a FRET pair (Trp/Dansyl) post-polymerization.
Claims7
A polymer comprising the repeating unit (Ib) or (Ic):
- wherein R is selected from the group consisting of H, C1-C20 alkyl, C2-C20 alkenyl, C3-C8 cycloalkyl, heterocyclyl, aryl, C1-C20 alkoxy, C1-C20 alkenyloxy, C3-C6 cycloalkyloxy, aryloxy, heterocyclyloxy, C1-C20 alkylamino, C1-C20 alkenylamino, C3-C8 cycloalkylamino, heterocyclylamino, or arylamino and may be optionally substituted with up to three substituents selected from halo, CN, NO2, oxo, alkyl, cycloalkyl, alkenyl, alkynyl, aralkyl, aryl, and a heterocyclic group;
- n is a number between 2 and 20;
- R1 through R6 are independently selected from the group consisting of H, aldehyde, C1-C20 alkyl, C2-C20 alkenyl, C3-C6 cycloalkyl, aryl, heterocyclyl, C1-C20 alkoxy, C1-C20 acyloxy, C2-C20 alkenyloxy, C3-C6 cycloalkyloxy, aryloxy, heterocyclyloxy, C1-C20 alkylamino, C2-C20 alkenylamino, C3-C8 cycloalkylamino, heterocyclylamino, arylamino, or halogen;
- R1 through R6 may be taken together to form a 5- to 7-membered ring which may be optionally substituted with up to three substituents selected from halo, CN, NO2, oxo, alkyl, cycloalkyl, alkenyl, alkynyl, aralkyl, aryl, or a heterocyclic group;
- A is a C2-C20 alkyl;
- with the proviso that any carbon-carbon double bonds in R or in R1 through R6 are essentially unreactive toward metathesis reactions with the catalyst.
3 more elements
Dependencies are inferred from the claim text.