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US 9,791,776 B2Granted
Resist composition and method for producing resist pattern
AssigneeSumitomo Chemical Company, Limited
InventorsKoji Ichikawa, Takahiro Yasue, Yuichi Mukai
Life of this patent
Estimating the term…
Abstract
A resist composition contains (A) a resin being insoluble or poorly soluble in alkali aqueous solution, but becoming soluble in an alkali aqueous solution by the action of an acid, (B) an acid generator represented by the formula (II), and (D) a compound represented by the formula (I), wherein R1 and R2, m and n, R3 and R4, X1, R5 and Z1+ are defined in the specification.
Claims2
A resist composition comprising
- (A) a resin being insoluble or poorly soluble in alkali aqueous solution, but becoming soluble in an alkali aqueous solution by the action of an acid, and having a structural unit represent by the formula (a1-1) or the formula (a1-2),
- (B) an acid generator represented by the formula (II), and
- (D) a compound represented by the formula (I),
- wherein R1 and R2 in each occurrence independently represent a C1 to C12 hydrocarbon group, a C1 to C6 alkoxyl group, a C2 to C7 acyl group, a C2 to C7 acyloxy group, a C2 to C7 alkoxycarbonyl group, a nitro group or a halogen atom;
- m and n independently represent an integer of 0 to 4;
- wherein R3 and R4 independently represent a fluorine atom or a C1 to C6 perfluoroalkyl group;
- X1 represents an C1 to C17 divalent saturated hydrocarbon group, and one or more hydrogen atom contained in the divalent saturated hydrocarbon group may be replaced by a fluorine atom, one or more —CH2— contained in the divalent saturated hydrocarbon group may be replaced by —O— or —CO—;
- R5 represents a group having cyclic ether structure;
- Z1+ represents an organic cation;
- and
- which further comprises a solvent,
- in each formula, La1 and La2 independently represent *—O— or *—O—(CH2)k1—CO—O—, k1 represents an integer of 1 to 7, * represents a bond to the carbonyl group;
- Ra4 and Ra5 independently represent a hydrogen atom or a methyl group;
- Ra6 and Ra7 independently represent a C1 to C8 alkyl group or a C3 to C10 alicyclic hydrocarbon group;
- m1 represents an integer 0 to 14;
- n1 represents an integer 0 to 10;
- and
- n1′ represents an integer 0 to 3,
- wherein R5 in the formula (II) is a group represented by the formula (IIA) or the formula (IIE),
- wherein s1 is 1 or 2
- t1 represents an integer of 0 to 2,
- provided that s1+t1 is 2 to 3;
- s11 represents an integer of 1 to 4,
- t11 represents an integer of 0 to 2;
- s12 is 1 or 2,
- t12 represents an integer of 0 to 2,
- provided that s12+t12 is 2 to 3;
- R6 in each occurrence represents a C1 to C12 saturated hydrocarbon group, a C6 to C18 aromatic hydrocarbon group, or two R6 are bonded together to form a ring, and one or more hydrogen atoms contained in the saturated hydrocarbon group, the aromatic hydrocarbon group and the ring may be replaced by a C1 to C6 alkyl group or a nitro group, and one or more —CH2— contained in the saturated hydrocarbon group and ring may be replaced by —O—;
- u1 represents an integer of 0 to 8;
- R7 and R8 in each occurrence independently represent a hydroxy group, a halogen atom, a C1 to C6 alkyl group, a C1 to C6 alkoxyl group, a C1 to C6 hydroxy alkyl group, a C2 to C7 acyl group, a C2 to C7 acyloxy group or a C2 to C7 acylamino group, or two of R7 and/or R8 may be bonded together to form a single bond or a ring;
- u2 and u3 independently represent an integer of 0 to 16;
- and
- * represents a bond to X1.
30 more elements
Dependencies are inferred from the claim text.