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US 9,790,450 B2Granted
Lubricating oil composition for engine made of aluminum alloy and lubrication method
AssigneeIdemitsu Kosan Co., Ltd.
InventorsJunya Iwasaki, Yasunori Shimizu, Yoriyuki Takashima
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Abstract
Lubricating oil compositions may include a base oil, a succinimide compound, and a thioheterocyclic compound. Such compositions may have a sulfur content of 0.10 mass % to 1.00 mass % based on a total amount of the composition. A phosphorus content represented by P in mass % and a sulfated ash content represented by M in mass %, based on the total amount of such compositions, may satisfy any of conditions A to C: condition A: P<0.03, and M<0.3; condition B: P<0.03 and 0.3≦M≦0.6; and condition C: 0.03≦P≦0.06 and M<0.3.
Claims10
A lubricating oil composition, comprising:
- a base oil;
- a first succinimide compound;
- a second succinimide compound;
- and
- a thioheterocyclic compound represented by formula (I):
- (R1)k—(S)m-AS-(S)n—(R2)l (I)
- where
- AS is a 1,3,4-thiadiazole ring;
- (S)m and (S)n are bonded to the 1,3,4-thiadiazole ring at the 2-position and the 5-position, respectively;
- each of R1 and R2 independently represents a hydrogen atom, an amino group, and a C1 to C50 group selected from the group consisting of an alkyl group, a cycloalkyl group, an alkenyl group, a cycloalkenyl group, and an aryl group, the C1 to C50 group optionally including at least one oxygen, nitrogen, or sulfur heteroatom;
- each of k, l, m, and n is an integer of 1 to 5;
- wherein:
- the first succinimide compound comprises at least one of an alkenylsuccinimide and an alkylsuccinimide;
- the second succinimide compound comprises at least one of a modified alkenylsuccinimide and a modified alkylsuccinimide;
- the second succinimide compound is modified with at least one of a boron compound and an organic acid;
- a boron content of the composition is 0.06 to 0.3 mass % based on a total mass of the composition;
- a ratio by mass of boron to nitrogen (B/N) in the composition is 0.25 to 1.0;
- a sulfur content of the composition is 0.10 mass % to 1.00 mass % based on a total mass of the composition;
- and
- a phosphorus content represented by P in mass % and a sulfated ash content represented by M in mass %, based on the total mass of the composition, satisfy any of conditions A to C:
- condition A:
- P<0.03, and M<0.3;
- condition B:
- P<0.03, and 0.3≦M≦0.6;
- and
- condition C:
- 0.03≦P≦0.06, and M<0.3.
24 more elements
Dependencies are inferred from the claim text.