Rubber composition for use in tire treads
AssigneeThe Yokohama Rubber Co., Ltd.
InventorsMasaki Sato, Satoshi Mihara, Yayoi Akahori, Shin Tsukishima, Ayumi Naka
Life of this patent
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Abstract
A rubber composition for use in tire treads comprising from 60 to 130 parts by weight of silica per 100 parts by weight of diene rubber containing not less than 50% by weight of hydroxyl group-containing modified styrene butadiene rubber, in which the weight ratio of oil to filler containing the silica is not greater than 0.25, and a silane coupling agent having a mercapto group and an Si—O bond is compounded in an amount from 4 to 15% by weight of the silica content, and diethylene glycol is compounded in an amount from 1 to 6% by weight of the silica content.
Claims11
A rubber composition for use in tire treads comprising:
- from 60 to 130 parts by weight of silica per 100 parts by weight of diene rubber containing not less than 50% by weight of hydroxyl group-containing modified styrene butadiene rubber,
- wherein:
- a weight ratio of oil with respect to filler containing the silica is not greater than 0.25,
- a silane coupling agent having a mercapto group and an Si—O bond is compounded in an amount from 4 to 15% by weight of the silica content,
- diethylene glycol is compounded in an amount from 1 to 6% by weight of the silica content;
- the silane coupling agent having a mercapto group and an Si—O bond is a mercaptosilane compound represented by general formula (2) below, or a copolymer having the structures of general formulas (3) and (4) below, or a polysiloxane having an average composition formula represented by general formula (5) below:
- (wherein R3, R4, and R5 are mutually independently selected from hydrogen, alkyl groups having from 1 to 8 carbons, alkoxy groups having from 1 to 8 carbons, linear polyether groups having a chain length of from 4 to 30, and aryl groups having from 6 to 30 carbons, and, at least one is the alkoxy group and at least one is the linear polyether group, and R6 is an alkylene group having from 1 to 30 carbons);
- (wherein R7 and R8 may form a ring structure, and R7 is selected from hydrogen, halogen, or alkyl groups or alkylene groups having from 1 to 30 carbons, alkenyl groups or alkenylene groups having from 2 to 30 carbons, alkynyl groups or alkynylene groups having from 2 to 30 carbons, and groups in which a terminal of the above alkyl group or alkenyl group is substituted with a hydroxyl group or carboxyl group;
- R8 is an alkylene group having from 1 to 30 carbons, an alkenylene group having from 2 to 30 carbons, or an alkynylene group having from 2 to 30 carbons;
- x is an integer of 1 or greater);
- (wherein R9 and R10 may form a ring structure, and R9 is selected from a hydrogen, halogen, or alkyl groups or alkylene groups having from 1 to 30 carbons, alkenyl groups or alkenylene groups having from 2 to 30 carbons, alkynyl groups or alkynylene groups having from 2 to 30 carbons, and groups in which a terminal of the above alkyl group or alkenyl group is substituted with a hydroxyl group or carboxyl group;
- R10 is an alkylene group having from 1 to 30 carbons, an alkenylene group having from 2 to 30 carbons, or an alkynylene group having from 2 to 30 carbons;
- y is an integer of 1 or greater);
- (A)a(B)b(C)c(D)d(R11)eSiO(4-2a-b-c-d-e)/2 (5)
- (wherein A is a bivalent organic group containing a sulfide group;
- B is a monovalent hydrocarbon group having from 5 to 10 carbons;
- C is a hydrolyzable group;
- D is an organic group containing a mercapto group;
- R11 is a monovalent hydrocarbon group having from 1 to 4 carbons;
- and a to e satisfy relationships 0≦a <1, 0≦b<a, 0<c<3, 0<d<1, 0≦e<2, and 0<2a+b+c+d+e<4;
- however, at least one of a and b is not 0).
Dependencies are inferred from the claim text.