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US 9,790,241 B2Granted
Reagent for enhancing generation of chemical species
AssigneesToyo Goesi Co., Ltd., Osaka University
InventorTakashi Miyazawa
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Abstract
A reagent that enhances acid generation of a photoacid generator and composition containing such reagent is disclosed.
Claims3
A composition comprising:
- a reagent and
- a precursor,
- wherein the reagent enhances the generation of a chemical species from the Precursor;
- wherein the reagent generates an intermediate by a first exposure using a light the wavelength of which is shorter than or equal to 15 nm;
- wherein a product is formed from the intermediate by a first elimination and a second elimination;
- wherein the product is excited by a second exposure using a light of which wavelength is longer than or equal to 300 nm;
- wherein the reagent transmutes into the product acting as a photosensitizer or acts as an acid generation enhancer;
- and
- wherein the reagent has a moiety represented by chemical Formula (I):
- where:
- each of M1 and M2 in chemical Formula (I) is a carbon atom;
- at least one of A, B, and C in chemical Formula (I) is hydrogen and the rest of A, B, and C in chemical Formula (I) is aryl;
- at least one of D and E in chemical Formula (I) is hydrogen and the rest of D and E in chemical Formula (I) is an aryl group;
- and
- F is selected from the group consisting of an organosilyl group, an organogermyl group, and an organotin group.
12 more elements
Dependencies are inferred from the claim text.