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US 9,789,470 B2Granted
Steam reforming catalyst and method of making thereof
AssigneeHaldor Topsoe A/S
InventorsJoachim Harteg Jacobsen, Charlotte Vinding Ovesen, Christian Daugaard
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Abstract
The invention provides a method for the production of a supported nickel catalyst, in which an aqueous mixture comprising an alkali metal salt plus other metal salts is sintered to form a support material. A supported nickel catalyst comprising potassium β-alumina is also provided.
Claims17
A method for the production of a supported nickel catalyst precursor with a sodium-β alumina phase and/or potassium-β alumina phase, said method comprising the steps of:
- i. providing a mixture comprising:
- i. a magnesium mineral or magnesium salt,
- ii. optionally, a calcium mineral or calcium salt,
- iii. an aluminium mineral or aluminium salt,
- iv. an alkali metal salt comprising at least one of Na and K, and
- v. optionally water;
- ii. extruding said mixture to form an extrudate, said extrudate containing integrated reservoirs of said alkali metal salt, and calcining the extrudate at a temperature from 300-600° C.;
- iii. sintering said calcined extrudate at a temperature in a range of 1100-14000° C. to form a support material;
- iv. impregnating said support material with an aqueous solution comprising a nickel salt to provide the supported nickel catalyst precursor;
- and
- v. optionally repeating step iv.
8 more elements
Dependencies are inferred from the claim text.