# US 9,775,351 B2 · Ternary fungicidal and pesticidal mixtures

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- Number: US 9,775,351 B2
- Document ID: US9775351B2
- Status: Granted
- Kind: B2
- Application number: 14/646,027
- Filed: 2013-11-28
- Published: 2015-10-22
- Granted: 2017-10-03
- Earliest claimed: 2012-11-30
- Assignees: Bayer CropScience AG
- Applicants: Bayer Cropscience AG
- Inventors: Haruko Sawada; Stefan Herrmann; Heiko Rieck; Christophe Dubost
- Web page: https://patentgrep.com/patent/US9775351B2

## CPC

- A01N 43/78: 1,3-Thiazoles; Hydrogenated 1,3-thiazoles
- A01N 37/22: the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
- A01N 43/56: 1,2-Diazoles; Hydrogenated 1,2-diazoles
- A01N: PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF (preservation of food or foodstuff A23); BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES (preparations for medical, dental or toiletry purposes which kill or prevent the growth or proliferation of unwanted organisms A61K); PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS

## Abstract

The present invention relates to novel mixtures, to processes for preparing these compounds, to compositions comprising these mixtures, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms or pests in crop protection and in the protection of materials and for enhancing plant health.

## Claims

### Claim 1

A fungicidal composition, comprising
(1) at least one compound of formula (I)
wherein
R1 represents a hydrogen atom or a methyl group and
R2 represents a methyl group, a difluoromethyl group or a trifluoromethyl group;
(2) (1.2) clothianidin; and
(3) Bacillus subtilis QRD1.045.

### Claim 2 (depends on 1)

A method for controlling harmful microorganisms, comprising contacting said harmful microorganisms and/or a habitat thereof with the composition according to claim 1.

### Claim 3 (depends on 1)

A method for treating seeds, comprising contacting said seeds with the composition according to claim 1.

### Claim 4 (depends on 1)

A process for preparing a composition, comprising mixing the composition according to claim 1 with an extender, a surfactant or a combination thereof.

### Claim 5 (depends on 1)

A seed treated with the composition according to claim 1.

### Claim 6 (depends on 1)

The composition of claim 1, wherein the active in the composition consists of the at least one compound of formula (I), (1.2) clothianidin; and Bacillus subtilis QRD 1.045.

### Claim 7 (depends on 1)

A composition according to claim 1, wherein compound (I) comprises the (S) enantiomer thereof.

### Claim 8 (depends on 1)

A composition according to claim 1, wherein compound (I) comprises the (R) enantiomer thereof.

### Claim 9 (depends on 1)

The composition of claim 1, wherein the ratios between each of the compound of formula (I) and (1.2) clothianidin is 25:1 to 1:25.

### Claim 10 (depends on 1)

The composition of claim 1, wherein the ratios between each of the compound of formula (I) and (1.2) clothianidin is 10:1 to 1:10.

### Claim 11 (depends on 1)

The composition of claim 1, wherein the ratios between each of the compound of formula (I) and (1.2) clothianidin is 5:1 to 1:5.

### Claim 12 (depends on 1)

The composition of claim 1, wherein
R1 is a hydrogen atom, and
R2 is a difluoromethyl group.

### Claim 13 (depends on 1)

The composition of claim 1, wherein the at least one compound of formula (I), (1.2) clothianidin, and Bacillus subtilis QRD1.045 are present in amounts to provide synergistic results.