# US 9,775,341 B2 · Composite material including a thermoplastic polymer, a pest food material and a pesticide

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- Number: US 9,775,341 B2
- Document ID: US9775341B2
- Status: Granted
- Kind: B2
- Application number: 14/790,691
- Filed: 2015-07-02
- Published: 2015-10-29
- Granted: 2017-10-03
- Earliest claimed: 2006-12-21
- Assignees: Dow AgroSciences LLC
- Applicants: Dow AgroSciences LLC
- Inventors: Robert L. Hill; James E. King; Joseph J. DeMark; Anton Arnoldy; Mike P. Tolley; Donald E. Williams, III; Joseph E. Eger, Jr.
- Web page: https://patentgrep.com/patent/US9775341B2

## CPC

- A01N 25/10: Macromolecular compounds
- A01M 1/02: with devices {or substances, e.g. food, pheronones} attracting the insects
- A01M 1/026: {combined with devices for monitoring insect presence, e.g. termites (bait stations A01M1/2005; detecting other animals in a given area A01M31/002)}
- A01M 1/2011: {for crawling insects}
- A01N 25/006: {insecticidal}
- A01N 43/56: 1,2-Diazoles; Hydrogenated 1,2-diazoles
- A01N 45/02: having three carbocyclic rings
- A01N 47/34: containing the groups [IMAGE cpc-sch-A01N-0947.gif], e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
- A01N 47/02: the carbon atom having no bond to a nitrogen atom
- A01N: PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF (preservation of food or foodstuff A23); BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES (preparations for medical, dental or toiletry purposes which kill or prevent the growth or proliferation of unwanted organisms A61K); PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01M: CATCHING, TRAPPING OR SCARING OF ANIMALS (appliances for catching swarms or drone-catching A01K57/00; fishing A01K69/00 - {A01K99/00}; biocides, pest repellants or attractants A01N); APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS

## Abstract

Composite materials that are palatable to a wood-destroying pest species and also pesticidal to the pest species can be used in pest control devices and can be used as wood substitutes for structural components, which are resistant to destruction by wood-destroying pests. The composite materials include a thermoplastic polymer, a food material for the pest and a pesticide. The composite material is formed by mixing a thermoplastic polymer, wood fragments or other cellulosic materials and a quantity of pesticide, and thereafter creating a molten material within a mixer, compounder, extruder or the like. The molten material is extruded or molded to form the desired shape.

## Claims

### Claim 1

A composite material for use in pest control, the composite material comprising:
a plastic structural matrix that comprises cellulose acetate butyrate (CAB);
a cellulosic food material that is palatable to a pest; and
a pesticide that is toxic to the pest
wherein the plastic structural matrix comprises from about 5% to about 50% by weight of the composite material, wherein the cellulosic food material comprises from about 50% to about 85% by weight of the composite material, and wherein the pesticide comprises from about 0.001% to about 5% by weight of the composite material, and
wherein the pesticide is noviflumuron.

### Claim 2 (depends on 1)

The composite material of claim 1 wherein the CAB is selected from the group consisting of CAB having a degree of polymerization from about 50 units to about 400 units, CAB having a degree of polymerization from about 100 units to about 300 units, CAB having a degree of polymerization of about 160 units, and a combination thereof.

### Claim 3 (depends on 1)

The composite material of claim 1 wherein the CAB comprises (a) a mixture of CAB having from about 50 monomer units to about 75 monomer units and CAB having from about 150 to about 300 monomer units, (b) a mixture of CAB having about 60 monomer units and CAB having about 300 monomer units, or (c) a mixture of CAB having about 64 monomer units and CAB having about 160 monomer units.

### Claim 4 (depends on 1)

The composite material of claim 1 wherein the CAB comprises a mixture of CAB having a molecular weight of about 16,000 and CAB having a molecular weight of about 40,000.

### Claim 5 (depends on 1)

The composite material of claim 1 wherein the cellulosic food material is selected from the group consisting of alpha cellulose, beta cellulose, gamma cellulose, preferred texture cellulose (PTC), wood, wood chips, wood fibers, sawdust, cardboard, paper, microcrystalline cellulose, and a combination thereof.

### Claim 6 (depends on 1)

The composite material of claim 1 wherein the cellulosic food material comprises a purified cellulose.

### Claim 7 (depends on 1)

The composite material of claim 1 wherein the pest comprises a cellulose-consuming organism.

### Claim 8 (depends on 1)

The composite material of claim 1 wherein the pest is selected from the group consisting of termites, carpenter ants, carpenter wasps, and a combination thereof.

### Claim 9 (depends on 1)

The composite material of claim 1 further comprising a stabilizer, processing aid, herbicide, fungicide, antimicrobial, bactericide, defoliant, safener, synergist, algaecide, attractant, desiccant, pheromone, repellant, animal dip, avicide, disinfectant, semiochemical, molluscicide, and a combination thereof.

### Claim 10 (depends on 1)

The composite material of claim 1 further comprising a lubricant.

### Claim 11 (depends on 10)

The composite material of claim 10 wherein the lubricant comprises up to about 5% by weight of the composite material.

### Claim 12 (depends on 1)

The composite material of claim 1 wherein the cellulosic food material comprises alpha cellulose.

### Claim 13 (depends on 1)

The composite material of claim 1 wherein the plastic structural matrix comprises from about 10% to about 40% by weight of the composite material, wherein the cellulosic food material comprises from about 60% to about 85% by weight of the composite material, and wherein the pesticide comprises from about 0.001% to about 5% by weight of the composite material.

### Claim 14 (depends on 1)

The composite material of claim 1 wherein the plastic structural matrix comprises from about 15% to about 30% by weight of the composite material, wherein the cellulosic food material comprises from about 70% to about 85% by weight of the composite material, and wherein the pesticide comprises from about 0.001% to about 5% by weight of the composite material.

### Claim 15 (depends on 1)

The composite material of claim 1 wherein the pesticide comprises from about 0.4% to about 5% by weight of the composite material.

### Claim 16

A composite material for use in pest control, the composite material comprising:
a plastic structural matrix that comprises cellulose acetate butyrate;
alpha cellulose contained in the plastic structural matrix; and
noviflumuron,
wherein the plastic structural matrix comprises from about 5% to about 50% by weight of the composite material, wherein the alpha cellulose comprises from about 50% to about 85% by weight of the composite material, and wherein the noviflumuron comprises from about 0.001% to about 5% by weight of the composite material.
